The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Remarkable Amplification of the Self‐Disproportionation of Enantiomers on Achiral‐Phase Chromatography Columns
Abstract
A phase they're going through: The enantiomers of chiral compounds containing a trifluoromethyl group directly bonded to a stereogenic carbon center are prone to self-disproportionation on columns of achiral silica gel (see picture). Thus, all fluorine-containing chiral reagents and drugs, as well as literature data on the stereochemical outcome of asymmetric transformations involving fluorine-containing compounds, should be reevaluated.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Kitamura, M., Suga, S., Oka, H., & Noyori, R. (1998) · Journal of the American Chemical Society · doi:10.1021/ja981740z · Cited by 229
L Amino Acids and D-Glucose Bind Stereospecifically to a Colloidal Clay
Bondy, S. C., & Harrington, M. E. (1979) · Science · doi:10.1126/science.424749 · Cited by 92
Origins of Chirality in Nature: A Reassessment of the Postulated Role of Bentonite
Youatt, J. B., & Brown, R. D. (1981) · Science · doi:10.1126/science.212.4499.1145 · Cited by 41
Cited by
Wang, J., Sánchez-Roselló, M., Aceña, J. L., del Pozo, C., Sorochinsky, A. E., Fustero, S., Soloshonok, V. A., & Liu, H. (2014) · Chemical Reviews · doi:10.1021/cr4002879 · Cited by 4,847
Self-citationXu, X.-H., Matsuzaki, K., & Shibata, N. (2015) · Chemical Reviews · doi:10.1021/cr500193b · Cited by 1,079
Recent advances in the trifluoromethylation methodology and new CF3-containing drugs
Zhu, W., Wang, J., Wang, S., Gu, Z., Aceña, J. L., Izawa, K., Liu, H., & Soloshonok, V. A. (2014) · Journal of Fluorine Chemistry · doi:10.1016/j.jfluchem.2014.06.026 · Cited by 493
Self-citationPeluso, P., & Chankvetadze, B. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00846 · Cited by 371
Han, J., Soloshonok, V. A., Klika, K. D., Drabowicz, J., & Wzorek, A. (2018) · Chemical Society Reviews · doi:10.1039/c6cs00703a · Cited by 287
Self-citation
Metadata
- Authors
- Soloshonok, V. A.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2006-01-17
- Volume
- 45
- Issue
- 5
- Pages
- 766-769
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2158531899
- Cited by
- 227
- References
- 3
- FWCI
- 4.19
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Remarkable Amplification of the Self‐Disproportionation of Enantiomers on Achiral‐Phase Chromatography Columns. https://app.cochat.ai/papers/10.1002/anie.200503373
- The paper
- Soloshonok, V. A. (2006). Remarkable Amplification of the Self‐Disproportionation of Enantiomers on Achiral‐Phase Chromatography Columns. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200503373
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.