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Intramolecular B–N Coordination as a Scaffold for Electron‐Transporting Materials: Synthesis and Properties of Boryl‐Substituted Thienylthiazoles
Abstract
Stacking the deck: Incorporation of boryl groups into the thienylthiazole system fixes the π-conjugated framework in a planar fashion by intramolecular B–N coordination. The dimer of boryl-substituted thienylthiazole forms a unique packing structure with offset face-to-face π stacking (see picture; B orange, N blue, S yellow, C turquoise) and films of it show high electron mobility.
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Cites
Electron Transport Materials for Organic Light-Emitting Diodes
Kulkarni, A. P., Tonzola, C. J., Babel, A., & Jenekhe, S. A. (2004) · Chemistry of Materials · doi:10.1021/cm049473l · Cited by 1,624
Cited by
BODIPY Dyes and Their Derivatives: Syntheses and Spectroscopic Properties
Loudet, A., & Burgess, K. (2007) · Chemical Reviews · doi:10.1021/cr078381n · Cited by 5,238
Long, X., Ding, Z., Dou, C., Zhang, J., Liu, J., & Wang, L. (2016) · Advanced Materials · doi:10.1002/adma.201601205 · Cited by 331
Tagare, J., & Vaidyanathan, S. (2018) · Journal of Materials Chemistry C · doi:10.1039/c8tc03689f · Cited by 284
Anthony, S. P. (2012) · ChemPlusChem · doi:10.1002/cplu.201200073 · Cited by 278
Rao, Y.-L., & Wang, S. (2011) · Inorganic Chemistry · doi:10.1021/ic200658v · Cited by 277
Metadata
- Authors
- Wakamiya, A., Taniguchi, T., & Yamaguchi, S.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2006-04-27
- Volume
- 45
- Issue
- 19
- Pages
- 3170-3173
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2103221532
- Cited by
- 331
- References
- 1
- FWCI
- 2.79
- Type
- journal article
- Language
- en
- Open access
- closed
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- Wakamiya, A., Taniguchi, T., & Yamaguchi, S. (2006). Intramolecular B–N Coordination as a Scaffold for Electron‐Transporting Materials: Synthesis and Properties of Boryl‐Substituted Thienylthiazoles. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200504391
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