The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Insulated Molecular Wires
Abstract
An astonishing assortment of structures have been described as “insulated molecular wires” (IMWs), thus illustrating the diversity of approaches to molecular‐scale insulation. These systems demonstrate the scope of encapsulation in the molecular engineering of optoelectronic materials and organic semiconductors. This Review surveys the synthesis and structural characterization of IMWs, and highlights emerging structure–property relationships to determine how insulation can enhance the behavior of a molecular wire. We focus mainly on three IMW architectures: polyrotaxanes, polymer‐wrapped π systems, and dendronized polymers, and compare the properties of these systems with those of conjugated polymers threaded through mesoporous frameworks and zeolites. Encapsulation of molecular wires can enhance properties as diverse as luminescence, electrical transport, and chemical stability, which points to applications in electroluminescent displays, sensors, and the photochemical generation of hydrogen.
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Cites
Synthesis of electrically conducting organic polymers: halogen derivatives of polyacetylene, (CH) x
Shirakawa, H., Louis, E. J., MacDiarmid, A. G., Chiang, C. K., & Heeger, A. J. (1977) · Journal of the Chemical Society, Chemical Communications · doi:10.1039/c39770000578 · Cited by 3,867
Cited by
Harada, A., Hashidzume, A., Yamaguchi, H., & Takashima, Y. (2009) · Chemical Reviews · doi:10.1021/cr9000622 · Cited by 892
Organic photonics for communications
Clark, J., & Lanzani, G. (2010) · Nature Photonics · doi:10.1038/nphoton.2010.160 · Cited by 823
Mechanically bonded macromolecules
Fang, L., Olson, M. A., Benítez, D., Tkatchouk, E., Goddard III, W. A., & Stoddart, J. F. (2010) · Chem. Soc. Rev. · doi:10.1039/b917901a · Cited by 450
Material properties and applications of mechanically interlocked polymers
Hart, L. F., Hertzog, J. E., Rauscher, P. M., Rawe, B. W., Tranquilli, M. M., & Rowan, S. J. (2021) · Nature Reviews Materials · doi:10.1038/s41578-021-00278-z · Cited by 336
Araki, J., & Ito, K. (2007) · Soft Matter · doi:10.1039/b705688e · Cited by 311
Metadata
- Authors
- Frampton, M. J., & Anderson, H. L.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2007-01-29
- Volume
- 46
- Issue
- 7
- Pages
- 1028-1064
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2075802365
- Cited by
- 596
- References
- 1
- FWCI
- 31.82
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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