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Cascade Reactions in Total Synthesis
Abstract
The design and implementation of cascade reactions is a challenging facet of organic chemistry, yet one that can impart striking novelty, elegance, and efficiency to synthetic strategies. The application of cascade reactions to natural products synthesis represents a particularly demanding task, but the results can be both stunning and instructive. This Review highlights selected examples of cascade reactions in total synthesis, with particular emphasis on recent applications therein. The examples discussed herein illustrate the power of these processes in the construction of complex molecules and underscore their future potential in chemical synthesis.
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Cites
Vitamin B12: Experiments Concerning the Origin of Its Molecular Structure
Eschenmoser, A. (1988) · Angewandte Chemie International Edition in English · doi:10.1002/anie.198800051 · Cited by 374
Cited by
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Anastas, P., & Eghbali, N. (2010) · Chem. Soc. Rev. · doi:10.1039/b918763b · Cited by 5,256
Asymmetric Aminocatalysis—Gold Rush in Organic Chemistry
Melchiorre, P., Marigo, M., Carlone, A., & Bartoli, G. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200705523 · Cited by 1,256
Semipinacol Rearrangement in Natural Product Synthesis
Song, Z.-L., Fan, C.-A., & Tu, Y.-Q. (2011) · Chemical Reviews · doi:10.1021/cr200055g · Cited by 544
Xuan, J., & Studer, A. (2017) · Chemical Society Reviews · doi:10.1039/c6cs00912c · Cited by 482
Bencivenni, G., Wu, L., Mazzanti, A., Giannichi, B., Pesciaioli, F., Song, M., Bartoli, G., & Melchiorre, P. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200903192 · Cited by 448
Metadata
- Authors
- Nicolaou, K. C., Edmonds, D. J., & Bulger, P. G.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2006-10-30
- Volume
- 45
- Issue
- 43
- Pages
- 7134-7186
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2152552837
- Cited by
- 2,101
- References
- 1
- FWCI
- 53.64
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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