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How Hydration Drastically Improves Adsorption Selectivity for CO2 over CH4 in the Flexible Chromium Terephthalate MIL‐53
Abstract
Taking a deep breath: The hydrated form of the microporous metal organic framework MIL-53(Cr) performs better than the dehydrated form for the selectivity binding of carbon dioxide over methane (see graph). The polarity of the adsorbed gas is thought to play a role in inducing framework flexibility and the breathing of the pores.
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Citations
Cited by
Metal–Organic Frameworks for Separations
Li, J.-R., Sculley, J., & Zhou, H.-C. (2012) · Chemical Reviews · doi:10.1021/cr200190s · Cited by 6,323
Carbon Dioxide Capture: Prospects for New Materials
D'Alessandro, D. M., Smit, B., & Long, J. R. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.201000431 · Cited by 4,046
Horike, S., Shimomura, S., & Kitagawa, S. (2009) · Nature Chemistry · doi:10.1038/nchem.444 · Cited by 2,486
CO2 capture by solid adsorbents and their applications: current status and new trends
Wang, Q., Luo, J., Zhong, Z., & Borgna, A. (2011) · Energy Environ. Sci. · doi:10.1039/c0ee00064g · Cited by 1,611
An Amine-Functionalized MIL-53 Metal−Organic Framework with Large Separation Power for CO 2 and CH 4
Couck, S., Denayer, J. F. M., Baron, G. V., Rémy, T., Gascon, J., & Kapteijn, F. (2009) · Journal of the American Chemical Society · doi:10.1021/ja900555r · Cited by 988
Metadata
- Authors
- Llewellyn, P. L., Bourrelly, S., Serre, C., Filinchuk, Y., & Férey, G.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2006-11-20
- Volume
- 45
- Issue
- 46
- Pages
- 7751-7754
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2128141951
- Cited by
- 447
- References
- 0
- FWCI
- 21.04
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: How Hydration Drastically Improves Adsorption Selectivity for CO2 over CH4 in the Flexible Chromium Terephthalate MIL‐53. https://app.cochat.ai/papers/10.1002/anie.200602278
- The paper
- Llewellyn, P. L., Bourrelly, S., Serre, C., Filinchuk, Y., & Férey, G. (2006). How Hydration Drastically Improves Adsorption Selectivity for CO2 over CH4 in the Flexible Chromium Terephthalate MIL‐53. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200602278
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
