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Near‐Monodisperse Tetrahedral Rhodium Nanoparticles on Charcoal: The Shape‐Dependent Catalytic Hydrogenation of Arenes
Open accessAbstract
The shape of things to come? Monodisperse (4.9±0.4)-nm tetrahedral rhodium nanoparticles on charcoal (▴/C) are compared to (4.8±0.4)-nm spherical rhodium nanoparticles on charcoal (•/C) and commercial Rh/C as a catalyst for the hydrogenation of anthracene (see picture). The former is 5.8- and 109-times more active than the latter two, respectively. It also shows a higher selectivity and excellent activity in the hydrogenation of several other arenes.
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Cited by
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Wu, B., & Zheng, N. (2013) · Nano Today · doi:10.1016/j.nantod.2013.02.006 · Cited by 461
Zaera, F. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00905 · Cited by 425
The Heat-Up Synthesis of Colloidal Nanocrystals
van Embden, J., Chesman, A. S. R., & Jasieniak, J. J. (2015) · Chemistry of Materials · doi:10.1021/cm5028964 · Cited by 414
Rodrigues, T. S., da Silva, A. G. M., & Camargo, P. H. C. (2019) · Journal of Materials Chemistry A · doi:10.1039/c9ta00074g · Cited by 357
Metadata
- Authors
- Park, K. H., Jang, K., Kim, H. J., & Son, S. U.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2007-01-29
- Volume
- 46
- Issue
- 7
- Pages
- 1152-1155
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2100111010
- Cited by
- 180
- References
- 0
- FWCI
- 5.38
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Park, K. H., Jang, K., Kim, H. J., & Son, S. U. (2007). Near‐Monodisperse Tetrahedral Rhodium Nanoparticles on Charcoal: The Shape‐Dependent Catalytic Hydrogenation of Arenes. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200603961
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