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Liquid‐Phase Catalytic Processing of Biomass‐Derived Oxygenated Hydrocarbons to Fuels and Chemicals

Open access
Chheda, Juben N., Huber, George W., Dumesic, James A.·2007·Angewandte Chemie International Edition

Abstract

Biomass has the potential to serve as a sustainable source of energy and organic carbon for our industrialized society. The focus of this Review is to present an overview of chemical catalytic transformations of biomass‐derived oxygenated feedstocks (primarily sugars and sugar‐alcohols) in the liquid phase to value‐added chemicals and fuels, with specific examples emphasizing the development of catalytic processes based on an understanding of the fundamental reaction chemistry. The key reactions involved in the processing of biomass are hydrolysis, dehydration, isomerization, aldol condensation, reforming, hydrogenation, and oxidation. Further, it is discussed how ideas based on fundamental chemical and catalytic concepts lead to strategies for the control of reaction pathways and process conditions to produce H 2/CO 2 or H 2/CO gas mixtures by aqueous‐phase reforming, to produce furan compounds by selective dehydration of carbohydrates, and to produce liquid alkanes by the combination of aldol condensation and dehydration/hydrogenation processes.

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Crossref · 10.1002/anie.200604274

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Metadata

Authors
Chheda, J. N., Huber, G. W., & Dumesic, J. A.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2007-09-17
Volume
46
Issue
38
Pages
7164-7183
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2150962987
Cited by
2,342
References
2
FWCI
53.49
Type
journal article
Language
en
Open access
green

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