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A Different Reaction Pathway for the Reduction of Aromatic Nitro Compounds on Gold Catalysts
Abstract
Golden distinction: With an Au/TiO2 catalyst, the formation of condensation products during the hydrogenation of aromatic nitro compounds is avoided. Macrokinetic experiments and in situ IR measurements, which showed that nitrosobenzene is generated in only small amounts and that hydroxylamine and nitrosobenzene interact strongly with the catalyst surface, led to the proposal of a novel reaction sequence (see figure).
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Citations
Cited by
Supported gold nanoparticles as catalysts for organic reactions
Corma, A., & Garcia, H. (2008) · Chemical Society Reviews · doi:10.1039/b707314n · Cited by 1,883
Self-citationHeterogeneous Catalysis for Tandem Reactions
Climent, M. J., Corma, A., Iborra, S., & Sabater, M. J. (2014) · ACS Catalysis · doi:10.1021/cs401052k · Cited by 361
Self-citationBUDRONI, G., & CORMA, A. (2008) · Journal of Catalysis · doi:10.1016/j.jcat.2008.05.031 · Cited by 118
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Metadata
- Authors
- Corma, A., Concepción, P., & Serna, P.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2007-09-17
- Volume
- 46
- Issue
- 38
- Pages
- 7266-7269
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2101425246
- Cited by
- 575
- References
- 0
- FWCI
- 9.12
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: A Different Reaction Pathway for the Reduction of Aromatic Nitro Compounds on Gold Catalysts. https://app.cochat.ai/papers/10.1002/anie.200700823
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- Corma, A., Concepción, P., & Serna, P. (2007). A Different Reaction Pathway for the Reduction of Aromatic Nitro Compounds on Gold Catalysts. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200700823
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