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How Is Oxygen Incorporated into Oxides? A Comprehensive Kinetic Study of a Simple Solid‐State Reaction with SrTiO3 as a Model Material
Abstract
The kinetics of stoichiometry change of an oxide—a prototype of a simple solid‐state reaction and a process of substantial technological relevance—is studied and analyzed in great detail. Oxygen incorporation into strontium titanate was chosen as a model process. The complete reaction can be phenomenologically and mechanistically understood beginning with the surface reaction and ending with the transport in the perovskite. Key elements are a detailed knowledge of the defect chemistry of the perovskite as well as the application of a variety of experimental and theoretical tools, many of them evolving from this study. The importance of the reaction and transport steps for (electro)chemical applications is emphasized.
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Cited by
Redox‐Based Resistive Switching Memories – Nanoionic Mechanisms, Prospects, and Challenges
Waser, R., Dittmann, R., Staikov, G., & Szot, K. (2009) · Advanced Materials · doi:10.1002/adma.200900375 · Cited by 5,080
Metadata
- Authors
- Merkle, R., & Maier, J.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2008-05-06
- Volume
- 47
- Issue
- 21
- Pages
- 3874-3894
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W1967140134
- Cited by
- 374
- References
- 0
- FWCI
- 7.75
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: How Is Oxygen Incorporated into Oxides? A Comprehensive Kinetic Study of a Simple Solid‐State Reaction with SrTiO3 as a Model Material. https://app.cochat.ai/papers/10.1002/anie.200700987
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- Merkle, R., & Maier, J. (2008). How Is Oxygen Incorporated into Oxides? A Comprehensive Kinetic Study of a Simple Solid‐State Reaction with SrTiO3 as a Model Material. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200700987
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
