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Diamonds are a Chemist's Best Friend: Diamondoid Chemistry Beyond Adamantane
Abstract
Marilyn Monroe knew that “diamonds are a girl's best friend” but, in the meantime, many chemists have realized that they are also extremely attractive objects in contemporary chemistry. The chemist's diamonds are usually quite small (herein: nanometer‐sized “diamondoids”) and as a result of their unique structure are unusual chemical building blocks. Since lower diamondoids (up to triamantane) have recently become available in large amounts from petroleum and higher diamondoids (starting from tetramantane) are now also accessible from crude oil new research involving them has begun to emerge. Having well‐defined structures makes these cage compounds so special compared to other nanometer‐scale diamonds. Selective and high‐yielding synthetic approaches to the functionalization of diamondoids gives derivatives that can find applications in, for example, polymers, coating materials, drugs, and molecular electronics.
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Brocks, J. J., Buick, R., Summons, R. E., & Logan, G. A. (2003) · Geochimica et Cosmochimica Acta · doi:10.1016/s0016-7037(03)00209-6 · Cited by 306
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The Lipophilic Bullet Hits the Targets: Medicinal Chemistry of Adamantane Derivatives
Wanka, L., Iqbal, K., & Schreiner, P. R. (2013) · Chemical Reviews · doi:10.1021/cr100264t · Cited by 696
Self-citationOvercoming lability of extremely long alkane carbon–carbon bonds through dispersion forces
Schreiner, P. R., Chernish, L. V., Gunchenko, P. A., Tikhonchuk, E. Y., Hausmann, H., Serafin, M., Schlecht, S., Dahl, J. E. P., Carlson, R. M. K., & Fokin, A. A. (2011) · Nature · doi:10.1038/nature10367 · Cited by 425
Self-citationLondon dispersion forces in sterically crowded inorganic and organometallic molecules
Liptrot, D. J., & Power, P. P. (2017) · Nature Reviews Chemistry · doi:10.1038/s41570-016-0004 · Cited by 371
Holste, K., Dietz, P., Scharmann, S., Keil, K., Henning, T., Zschätzsch, D., Reitemeyer, M., Nauschütt, B., Kiefer, F., Kunze, F., et al. (2020) · Review of Scientific Instruments · doi:10.1063/5.0010134 · Cited by 207
Metadata
- Authors
- Schwertfeger, H., Fokin, A. A., & Schreiner, P. R.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2008-01-21
- Volume
- 47
- Issue
- 6
- Pages
- 1022-1036
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2023284292
- Cited by
- 413
- References
- 1
- FWCI
- 6.22
- Type
- journal article
- Language
- en
- Open access
- closed
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- Schwertfeger, H., Fokin, A. A., & Schreiner, P. R. (2008). Diamonds are a Chemist's Best Friend: Diamondoid Chemistry Beyond Adamantane. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200701684
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