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Dinuclear {(salen)Al} Complexes Display Expanded Scope in the Conjugate Cyanation of α,β‐Unsaturated Imides
Open accessAbstract
Al together: Covalently linked dinuclear {(salen)Al} complexes catalyze the conjugate cyanation of α,β-unsaturated imides with several orders of magnitude greater reactivity over the mononuclear analogue, and with comparable enantioselectivity. Imides that were completely unreactive with homo- and heterobimetallic combinations of mononuclear catalysts can now be converted into the corresponding cyanation products with high enantiomeric excess.
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Cited by
Recent advances in cooperative bimetallic asymmetric catalysis: dinuclear Schiff base complexes
Matsunaga, S., & Shibasaki, M. (2014) · Chem. Commun. · doi:10.1039/c3cc47587e · Cited by 263
Ford, D. D., Nielsen, L. P. C., Zuend, S. J., Musgrave, C. B., & Jacobsen, E. N. (2013) · Journal of the American Chemical Society · doi:10.1021/ja408027p · Cited by 138
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Metadata
- Authors
- Mazet, C., & Jacobsen, E. N.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2008-02-11
- Volume
- 47
- Issue
- 9
- Pages
- 1762-1765
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2143975870
- Cited by
- 166
- References
- 0
- FWCI
- 10.89
- Type
- journal article
- Language
- en
- Open access
- green
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- CoChat. (2026). Citation check: Dinuclear {(salen)Al} Complexes Display Expanded Scope in the Conjugate Cyanation of α,β‐Unsaturated Imides. https://app.cochat.ai/papers/10.1002/anie.200704461
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- Mazet, C., & Jacobsen, E. N. (2008). Dinuclear {(salen)Al} Complexes Display Expanded Scope in the Conjugate Cyanation of α,β‐Unsaturated Imides. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200704461
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