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Asymmetric Organocatalysis: From Infancy to Adolescence
Abstract
After an initial period of validating asymmetric organocatalysis by using a wide range of important model reactions that constitute the essential tools of organic synthesis, the time has now been reached when organocatalysis can be used to address specific issues and solve pending problems of stereochemical relevance. This Review deals with selected studies reported in 2006 and the first half of 2007, and is intended to highlight four main aspects that may be taken as testimony of the present status and prospective of organocatalysis: a) chemical efficiency; b) discovery of new substrate combinations to give new asymmetric syntheses; c) development of new catalysts for specific purposes by using mechanistic findings; and d) applications of organocatalytic reactions in the asymmetric total synthesis of target natural products and known compounds of biological and pharmaceutical relevance.
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Cites
Tornøe, C. W., Christensen, C., & Meldal, M. (2002) · The Journal of Organic Chemistry · doi:10.1021/jo011148j · Cited by 8,696
Plausible origins of homochirality in the amino acid catalyzed neogenesis of carbohydrates
Córdova, A., Engqvist, M., Ibrahem, I., Casas, J., & Sundén, H. (2005) · Chem. Commun. · doi:10.1039/b500589b · Cited by 127
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Parmar, D., Sugiono, E., Raja, S., & Rueping, M. (2014) · Chemical Reviews · doi:10.1021/cr5001496 · Cited by 2,118
Asymmetric Aminocatalysis—Gold Rush in Organic Chemistry
Melchiorre, P., Marigo, M., Carlone, A., & Bartoli, G. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200705523 · Cited by 1,256
Photoredox Catalysis with Visible Light
Zeitler, K. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200904056 · Cited by 991
Albrecht, Ł., Jiang, H., & Jørgensen, K. A. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201102522 · Cited by 466
Metadata
- Authors
- Dondoni, A., & Massi, A.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2008-06-03
- Volume
- 47
- Issue
- 25
- Pages
- 4638-4660
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2166399067
- Cited by
- 1,252
- References
- 2
- FWCI
- 80.22
- Type
- journal article
- Language
- en
- Open access
- closed
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