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In Situ Multinuclear NMR Spectroscopic Studies of the Thermal Decomposition of Ammonia Borane in Solution
Abstract
Looking to the future: The decomposition in solution of a potential hydrogen-storage compound, ammonia borane (AB), was investigated by in situ 11B NMR spectroscopy and ex situ 15N NMR spectroscopy. The reaction was found to be second order in AB with an activation barrier of (25±2) kcal mol−1. The second-order kinetics have implications for the use of solutions containing AB in high concentrations for hydrogen storage.
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Citations
Cited by
Ammonia-Borane and Related Compounds as Dihydrogen Sources
Staubitz, A., Robertson, A. P. M., & Manners, I. (2010) · Chemical Reviews · doi:10.1021/cr100088b · Cited by 1,247
B–N compounds for chemical hydrogenstorage
Hamilton, C. W., Baker, R. T., Staubitz, A., & Manners, I. (2009) · Chem. Soc. Rev. · doi:10.1039/b800312m · Cited by 1,087
Self-citationAmmonia Borane as a Hydrogen Carrier: Dehydrogenation and Regeneration
Smythe, N. C., & Gordon, J. C. (2010) · European Journal of Inorganic Chemistry · doi:10.1002/ejic.200900932 · Cited by 347
Huang, Z., & Autrey, T. (2012) · Energy & Environmental Science · doi:10.1039/c2ee23039a · Cited by 268
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Metadata
- Authors
- Shaw, W. J., Linehan, J. C., Szymczak, N. K., Heldebrant, D. J., Yonker, C., Camaioni, D. M., Baker, R. T., & Autrey, T.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2008-09-09
- Volume
- 47
- Issue
- 39
- Pages
- 7493-7496
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2118412542
- Cited by
- 190
- References
- 0
- FWCI
- 9.94
- Type
- journal article
- Language
- en
- Open access
- closed
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- Shaw, W. J., Linehan, J. C., Szymczak, N. K., Heldebrant, D. J., Yonker, C., Camaioni, D. M., Baker, R. T., & Autrey, T. (2008). In Situ Multinuclear NMR Spectroscopic Studies of the Thermal Decomposition of Ammonia Borane in Solution. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200802100
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