The DOI matches its Crossref record.
Heterolytic Dihydrogen Activation by a Frustrated Carbene–Borane Lewis Pair
Abstract
Relief from frustration: The sterically demanding carbene 1,3-di-tert-butylimidazolin-2-ylidene and B(C6F5)3, a “frustrated” Lewis pair, is a viable system for the activation of CO, HH, and CH bonds. However, slow rearrangement to an abnormal carbene–borane adduct allows the irreversible formation of a strong BC bond and enables this system to circumvent frustration at the expense of its activity.
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Citations
Cited by
B–N compounds for chemical hydrogenstorage
Hamilton, C. W., Baker, R. T., Staubitz, A., & Manners, I. (2009) · Chem. Soc. Rev. · doi:10.1039/b800312m · Cited by 1,087
Wang, Q., Zhao, W., He, J., Zhang, Y., & Chen, E. Y.-X. (2017) · Macromolecules · doi:10.1021/acs.macromol.6b02398 · Cited by 127
Metadata
- Authors
- Holschumacher, D., Bannenberg, T., Hrib, C. G., Jones, P. G., & Tamm, M.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2008-09-09
- Volume
- 47
- Issue
- 39
- Pages
- 7428-7432
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2115378983
- Cited by
- 393
- References
- 0
- FWCI
- 22.61
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Heterolytic Dihydrogen Activation by a Frustrated Carbene–Borane Lewis Pair. https://app.cochat.ai/papers/10.1002/anie.200802705
- The paper
- Holschumacher, D., Bannenberg, T., Hrib, C. G., Jones, P. G., & Tamm, M. (2008). Heterolytic Dihydrogen Activation by a Frustrated Carbene–Borane Lewis Pair. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200802705
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
