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[Al4(OH)2(OCH3)4(H2N‐bdc)3]⋅x H2O: A 12‐Connected Porous Metal–Organic Framework with an Unprecedented Aluminum‐Containing Brick
Abstract
Al together now! A new stable aluminum aminoterephthalate system contains octameric building blocks that are connected by organic linkers to form a 12‐connected net (see picture). The structure adopts a cubic centered packing motive in which octameric units replace individual atoms, thus forming distorted octahedral (red sphere) and tetrahedral cages (green spheres) with effective accessible diameters of 1 and 0.45 nm, respectively.magnified image
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Citations
Cites
An Amine-Functionalized MIL-53 Metal−Organic Framework with Large Separation Power for CO 2 and CH 4
Couck, S., Denayer, J. F. M., Baron, G. V., Rémy, T., Gascon, J., & Kapteijn, F. (2009) · Journal of the American Chemical Society · doi:10.1021/ja900555r · Cited by 988
Cited by
Valenzano, L., Civalleri, B., Chavan, S., Bordiga, S., Nilsen, M. H., Jakobsen, S., Lillerud, K. P., & Lamberti, C. (2011) · Chemistry of Materials · doi:10.1021/cm1022882 · Cited by 1,919
Yusuf, V. F., Malek, N. I., & Kailasa, S. K. (2022) · ACS Omega · doi:10.1021/acsomega.2c05310 · Cited by 894
Metadata
- Authors
- Ahnfeldt, T., Guillou, N., Gunzelmann, D., Margiolaki, I., Loiseau, T., Férey, G., Senker, J., & Stock, N.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2009-06-25
- Volume
- 48
- Issue
- 28
- Pages
- 5163-5166
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2110151257
- Cited by
- 329
- References
- 1
- FWCI
- 16.38
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: [Al4(OH)2(OCH3)4(H2N‐bdc)3]⋅x H2O: A 12‐Connected Porous Metal–Organic Framework with an Unprecedented Aluminum‐Containing Brick. https://app.cochat.ai/papers/10.1002/anie.200901409
- The paper
- Ahnfeldt, T., Guillou, N., Gunzelmann, D., Margiolaki, I., Loiseau, T., Férey, G., Senker, J., & Stock, N. (2009). [Al4(OH)2(OCH3)4(H2N‐bdc)3]⋅x H2O: A 12‐Connected Porous Metal–Organic Framework with an Unprecedented Aluminum‐Containing Brick. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200901409
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
