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The Effect of Pressure on ZIF‐8: Increasing Pore Size with Pressure and the Formation of a High‐Pressure Phase at 1.47 GPa
Open accessAbstract
The big squeeze: On applying pressure to ZIF-8 (0.18 GPa), solvent can be squeezed into the porous cavities, initially increasing the pore size and unit-cell volume. On increasing pressure further to 1.47 GPa, a phase transition takes place (see picture). This transition allows more solvent to enter the original nanopores and enlarges the narrow channels connecting these pores, resulting in higher porous volume and solvent content.
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Citations
Cited by
Tan, J. C., & Cheetham, A. K. (2011) · Chemical Society Reviews · doi:10.1039/c0cs00163e · Cited by 762
Self-citationChizallet, C., Lazare, S., Bazer-Bachi, D., Bonnier, F., Lecocq, V., Soyer, E., Quoineaud, A.-A., & Bats, N. (2010) · Journal of the American Chemical Society · doi:10.1021/ja103365s · Cited by 586
Tan, J. C., Bennett, T. D., & Cheetham, A. K. (2010) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1003205107 · Cited by 552
Self-citationCoudert, F.-X. (2015) · Chemistry of Materials · doi:10.1021/acs.chemmater.5b00046 · Cited by 528
Metadata
- Authors
- Moggach, S. A., Bennett, T. D., & Cheetham, A. K.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2009-09
- Volume
- 48
- Issue
- 38
- Pages
- 7087-7089
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2147397013
- Cited by
- 530
- References
- 0
- FWCI
- 11.99
- Type
- journal article
- Language
- en
- Open access
- green
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- CoChat. (2026). Citation check: The Effect of Pressure on ZIF‐8: Increasing Pore Size with Pressure and the Formation of a High‐Pressure Phase at 1.47 GPa. https://app.cochat.ai/papers/10.1002/anie.200902643
- The paper
- Moggach, S. A., Bennett, T. D., & Cheetham, A. K. (2009). The Effect of Pressure on ZIF‐8: Increasing Pore Size with Pressure and the Formation of a High‐Pressure Phase at 1.47 GPa. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200902643
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