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A Crystal‐Engineered Hydrogen‐Bonded Octachloroperylene Diimide with a Twisted Core: An n‐Channel Organic Semiconductor

Gsänger, Marcel, Oh, Joon Hak, Könemann, Martin, Höffken, Hans Wolfgang, Krause, Ana‐Maria, Bao, Zhenan, Würthner, Frank·2010·Angewandte Chemie International Edition

Abstract

Twisted up: Perchlorination of perylene diimide afforded an exceptionally electron-poor organic semiconductor molecule (see picture; C black, Cl green, O red, N blue, H white) that crystallizes in an ideal brickstone arrangement with close π–π and chlorine–chlorine contacts. Vapor-deposited thin films of this molecule show excellent transistor performance, even in air (μ≈0.8 cm2 V−1 s−1, Ion/Ioff≈108).

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Metadata

Authors
Gsänger, M., Oh, J. H., Könemann, M., Höffken, H. W., Krause, A., Bao, Z., & Würthner, F.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2010-01-13
Volume
49
Issue
4
Pages
740-743
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2105868336
Cited by
383
References
0
FWCI
21.12
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: A Crystal‐Engineered Hydrogen‐Bonded Octachloroperylene Diimide with a Twisted Core: An n‐Channel Organic Semiconductor. https://app.cochat.ai/papers/10.1002/anie.200904215
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Gsänger, M., Oh, J. H., Könemann, M., Höffken, H. W., Krause, A., Bao, Z., & Würthner, F. (2010). A Crystal‐Engineered Hydrogen‐Bonded Octachloroperylene Diimide with a Twisted Core: An n‐Channel Organic Semiconductor. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200904215

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