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Light‐Driven Hydrogen Generation: Efficient Iron‐Based Water Reduction Catalysts
Abstract
Let your light shine: A novel state-of-the-art system for light-driven proton reduction with iron catalysts was developed (see scheme; SR=sacrificial reagent). It consists of simple iron carbonyl complexes such as [Fe3(CO)12], triethylamine as sacrificial reagent (electron donor), and [Ir(bpy)(ppy)2]PF6 as photosensitizer (PS). High turnover numbers of more than 3000 for the sensitizer and 400 for the iron catalyst are obtained.
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Cited by
Fürstner, A. (2016) · ACS Central Science · doi:10.1021/acscentsci.6b00272 · Cited by 746
You, Y., & Nam, W. (2012) · Chemical Society Reviews · doi:10.1039/c2cs35171d · Cited by 668
Metal-complex chromophores for solar hydrogen generation
Yuan, Y.-J., Yu, Z.-T., Chen, D.-Q., & Zou, Z.-G. (2017) · Chemical Society Reviews · doi:10.1039/c6cs00436a · Cited by 423
Singh, W. M., Baine, T., Kudo, S., Tian, S., Ma, X. A. N., Zhou, H., DeYonker, N. J., Pham, T. C., Bollinger, J. C., Baker, D. L., et al. (2012) · Angewandte Chemie · doi:10.1002/ange.201200082 · Cited by 66
Metadata
- Authors
- Gärtner, F., Sundararaju, B., Surkus, A., Boddien, A., Loges, B., Junge, H., Dixneuf, P. H., & Beller, M.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2009-12-15
- Volume
- 48
- Issue
- 52
- Pages
- 9962-9965
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2156976286
- Cited by
- 181
- References
- 0
- FWCI
- 11.07
- Type
- journal article
- Language
- en
- Open access
- closed
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- Gärtner, F., Sundararaju, B., Surkus, A., Boddien, A., Loges, B., Junge, H., Dixneuf, P. H., & Beller, M. (2009). Light‐Driven Hydrogen Generation: Efficient Iron‐Based Water Reduction Catalysts. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200905115
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