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A Recyclable Nanoparticle‐Supported Palladium Catalyst for the Hydroxycarbonylation of Aryl Halides in Water
Abstract
Boomerang catalysis: A catalyst catch–release system is established by the noncovalent attachment of a Pd N-heterocyclic carbene complex to graphene-coated magnetic Co nanoparticles. The immobilization by pyrene tags (see scheme; blue) is reversible at elevated temperatures, releasing the homogeneous catalyst. The hydroxycarbonylation of aryl halides is performed in 16 iterative reactions with this highly active catalyst.
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Cites
Noncovalent sidewall functionalization of single-walled carbon nanotubes for protein immobilization
Chen, R. J., Zhang, Y., Wang, D., & Dai, H. (2001) · Journal of the American Chemical Society · doi:10.1021/ja010172b · Cited by 2,534
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The recent development of efficient Earth-abundant transition-metal nanocatalysts
Wang, D., & Astruc, D. (2017) · Chemical Society Reviews · doi:10.1039/c6cs00629a · Cited by 608
Asymmetric Nanocatalysis: N‐Heterocyclic Carbenes as Chiral Modifiers of Fe3O4/Pd nanoparticles
Ranganath, K. V. S., Kloesges, J., Schäfer, A. H., & Glorius, F. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.201002782 · Cited by 337
Kainz, Q. M., & Reiser, O. (2014) · Accounts of Chemical Research · doi:10.1021/ar400236y · Cited by 304
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Metadata
- Authors
- Wittmann, S., Schätz, A., Grass, R. N., Stark, W. J., & Reiser, O.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2010-02-22
- Volume
- 49
- Issue
- 10
- Pages
- 1867-1870
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2157546476
- Cited by
- 225
- References
- 1
- FWCI
- 12.31
- Type
- journal article
- Language
- en
- Open access
- closed
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- Wittmann, S., Schätz, A., Grass, R. N., Stark, W. J., & Reiser, O. (2010). A Recyclable Nanoparticle‐Supported Palladium Catalyst for the Hydroxycarbonylation of Aryl Halides in Water. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200906166
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