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Dilution‐Induced Self‐Assembly of Porphyrin Aggregates: A Consequence of Coupled Equilibria
Open accessAbstract
Piggy-back porphyrins: The presence of a Lewis base remarkably affects the cooperative self-assembly of zinc porphyrins. Driven by the susceptibility of the monomer towards the axial ligand, monomer scavenging caused depolymerization of porphyrin aggregates, and dilution caused aggregation by a re-entrant phase transition. Model predictions were validated by dilution experiments.
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Citations
Cited by
Supramolecular Chirality in Self-Assembled Systems
Liu, M., Zhang, L., & Wang, T. (2015) · Chemical Reviews · doi:10.1021/cr500671p · Cited by 2,250
Hydrogen-bonded Supramolecular π-Functional Materials
González-Rodríguez, D., & Schenning, A. P. H. J. (2011) · Chemistry of Materials · doi:10.1021/cm101817h · Cited by 426
Self-citationSelection of supramolecular chirality by application of rotational and magnetic forces
Micali, N., Engelkamp, H., van Rhee, P. G., Christianen, P. C. M., Scolaro, L. M., & Maan, J. C. (2012) · Nature Chemistry · doi:10.1038/nchem.1264 · Cited by 259
Self-citationWelcome home, systems chemists
von Kiedrowski, G., Otto, S., & Herdewijn, P. (2010) · Journal of Systems Chemistry · doi:10.1186/1759-2208-1-1 · Cited by 102
Metadata
- Authors
- Helmich, F., Lee, C. C., Nieuwenhuizen, M. M. L., Gielen, J. C., Christianen, P. C. M., Larsen, A., Fytas, G., Leclère, P. E. L. G., Schenning, A. P. H. J., & Meijer, E. W.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2010-05-17
- Volume
- 49
- Issue
- 23
- Pages
- 3939-3942
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2132828096
- Cited by
- 168
- References
- 0
- FWCI
- 6.33
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Helmich, F., Lee, C. C., Nieuwenhuizen, M. M. L., Gielen, J. C., Christianen, P. C. M., Larsen, A., Fytas, G., Leclère, P. E. L. G., Schenning, A. P. H. J., & Meijer, E. W. (2010). Dilution‐Induced Self‐Assembly of Porphyrin Aggregates: A Consequence of Coupled Equilibria. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201000162
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