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Cited by 238

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A Modular and Size‐Selective Synthesis of [n]Cycloparaphenylenes: A Step toward the Selective Synthesis of [n,n] Single‐Walled Carbon Nanotubes

Omachi, Haruka, Matsuura, Sanae, Segawa, Yasutomo, Itami, Kenichiro·2010·Angewandte Chemie International Edition

Abstract

A modular strategy served in the size-selective syntheses of [14]-, [15]-, and [16]cycloparaphenylenes (CPPs). A Suzuki–Miyaura coupling was used to assemble a terphenyl-equivalent, L-shaped cis-1,4-diphenylcyclohexane unit and a linear benzene/biphenyl unit in a 3+1+3 or 3+2+3 mode to give U-shaped septi- and octiphenyl units. The cyclizative dimerization of these U-shaped units and subsequent aromatization yielded the CPPs.

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Metadata

Authors
Omachi, H., Matsuura, S., Segawa, Y., & Itami, K.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2010-11-23
Volume
49
Issue
52
Pages
10202-10205
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2124586267
Cited by
238
References
1
FWCI
10.89
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: A Modular and Size‐Selective Synthesis of [n]Cycloparaphenylenes: A Step toward the Selective Synthesis of [n,n] Single‐Walled Carbon Nanotubes. https://app.cochat.ai/papers/10.1002/anie.201005734
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Omachi, H., Matsuura, S., Segawa, Y., & Itami, K. (2010). A Modular and Size‐Selective Synthesis of [n]Cycloparaphenylenes: A Step toward the Selective Synthesis of [n,n] Single‐Walled Carbon Nanotubes. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201005734

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