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Active Oxygen on a Au/TiO2 Catalyst: Formation, Stability, and CO Oxidation Activity
Abstract
Ideal location: The active oxygen for CO oxidation on Au/TiO2 catalysts is a highly stable oxygen species, whose formation is facile and hardly activated. This species is proposed to be surface lattice oxygen at the perimeter of the Au–TiO2 interface, activated by the presence of the Au nanoparticle. At higher temperatures, thermally activated Olatt migration also gives access to adjacent Olatt species.
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Cited by
On the Synergetic Catalytic Effect in Heterogeneous Nanocomposite Catalysts
Shi, J. (2013) · Chemical Reviews · doi:10.1021/cr3002752 · Cited by 652
Raman Spectra of Polycrystalline CeO2: A Density Functional Theory Study
Schilling, C., Hofmann, A., Hess, C., & Ganduglia-Pirovano, M. V. (2017) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.7b06643 · Cited by 513
Metadata
- Authors
- Widmann, D., & Behm, R. J.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2011-07-20
- Volume
- 50
- Issue
- 43
- Pages
- 10241-10245
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2060002843
- Cited by
- 359
- References
- 0
- FWCI
- 14.10
- Type
- journal article
- Language
- en
- Open access
- closed
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- Widmann, D., & Behm, R. J. (2011). Active Oxygen on a Au/TiO2 Catalyst: Formation, Stability, and CO Oxidation Activity. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201102062
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.