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Fused Indolines by Palladium‐Catalyzed Asymmetric CC Coupling Involving an Unactivated Methylene Group
Open accessAbstract
Selectivity at high temperatures: Bulky, thermally stable, chiral palladium complexes generated from N-heterocyclic carbenes (NHCs; see picture) were successfully applied to the synthesis of highly enantioenriched trans-fused indolines. Remarkably, this reaction occurs at elevated temperatures with excellent asymmetric recognition of an enantiotopic CH bond in an unactivated methylene unit.
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Cited by
Organocatalysis in Inert C–H Bond Functionalization
Qin, Y., Zhu, L., & Luo, S. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00657 · Cited by 785
Transition-Metal-Catalyzed, Coordination-Assisted Functionalization of Nonactivated C(sp3)–H Bonds
Liu, B., Romine, A. M., Rubel, C. Z., Engle, K. M., & Shi, B.-F. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00519 · Cited by 538
Engle, K. M., & Yu, J.-Q. (2013) · The Journal of Organic Chemistry · doi:10.1021/jo400159y · Cited by 531
Enantioselective amine α-functionalization via palladium-catalysed C–H arylation of thioamides
Jain, P., Verma, P., Xia, G., & Yu, J.-Q. (2017) · Nature Chemistry · doi:10.1038/nchem.2619 · Cited by 336
Metadata
- Authors
- Nakanishi, M., Katayev, D., Besnard, C., & Kündig, E. P.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2011-07
- Volume
- 50
- Issue
- 32
- Pages
- 7438-7441
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2112943497
- Cited by
- 314
- References
- 0
- FWCI
- 16.16
- Type
- journal article
- Language
- en
- Open access
- green
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- Nakanishi, M., Katayev, D., Besnard, C., & Kündig, E. P. (2011). Fused Indolines by Palladium‐Catalyzed Asymmetric CC Coupling Involving an Unactivated Methylene Group. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201102639
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