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Improved Ruthenium‐Catalyzed Amination of Alcohols with Ammonia: Synthesis of Diamines and Amino Esters
Abstract
Diamination of diols: The first homogeneously catalyzed diaminations of primary and secondary diols with ammonia give the corresponding diamines. Other primary as well as secondary alcohols including hydroxy-substituted esters can also be efficiently converted to primary amines. This atom-efficient and selective amination method proceeds in an ammonia atmosphere without additional hydrogen sources.
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Citations
Cites
Chemical Routes for the Transformation of Biomass into Chemicals
Corma, A., Iborra, S., & Velty, A. (2007) · Chemical Reviews · doi:10.1021/cr050989d · Cited by 5,970
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Gunanathan, C., & Milstein, D. (2013) · Science · doi:10.1126/science.1229712 · Cited by 1,542
Alternative Monomers Based on Lignocellulose and Their Use for Polymer Production
Delidovich, I., Hausoul, P. J. C., Deng, L., Pfützenreuter, R., Rose, M., & Palkovits, R. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00354 · Cited by 773
Isosorbide as a Renewable Platform chemical for Versatile Applications—Quo Vadis?
Rose, M., & Palkovits, R. (2012) · ChemSusChem · doi:10.1002/cssc.201100580 · Cited by 440
Homogeneous catalysis for the conversion of biomass and biomass-derived platform chemicals
Deuss, P. J., Barta, K., & de Vries, J. G. (2014) · Catal. Sci. Technol. · doi:10.1039/c3cy01058a · Cited by 316
Metadata
- Authors
- Imm, S., Bähn, S., Zhang, M., Neubert, L., Neumann, H., Klasovsky, F., Pfeffer, J., Haas, T., & Beller, M.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2011-07-05
- Volume
- 50
- Issue
- 33
- Pages
- 7599-7603
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W1977420451
- Cited by
- 244
- References
- 1
- FWCI
- 13.31
- Type
- journal article
- Language
- en
- Open access
- closed
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- The paper
- Imm, S., Bähn, S., Zhang, M., Neubert, L., Neumann, H., Klasovsky, F., Pfeffer, J., Haas, T., & Beller, M. (2011). Improved Ruthenium‐Catalyzed Amination of Alcohols with Ammonia: Synthesis of Diamines and Amino Esters. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201103199
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