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On the Interpretation of Deuterium Kinetic Isotope Effects in CH Bond Functionalizations by Transition‐Metal Complexes
Abstract
Rate versus selectivity determining: The measurement of a kinetic isotope effect (KIE) can provide valuable information about the mechanism of a reaction, but care must be taken in the design and interpretation of KIE experiments. Depending on the experiment that is conducted, the observation of a primary KIE resulting from H/D substitution does not necessarily imply that CH bond cleavage occurs during the rate-determining step of a reaction. FG=functional group.
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Cited by
Jiao, K.-J., Xing, Y.-K., Yang, Q.-L., Qiu, H., & Mei, T.-S. (2020) · Accounts of Chemical Research · doi:10.1021/acs.accounts.9b00603 · Cited by 760
Photochemical Nickel-Catalyzed C–H Arylation: Synthetic Scope and Mechanistic Investigations
Heitz, D. R., Tellis, J. C., & Molander, G. A. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b04789 · Cited by 518
Nandy, A., Duan, C., Taylor, M. G., Liu, F., Steeves, A. H., & Kulik, H. J. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00347 · Cited by 358
Matera, S., Schneider, W. F., Heyden, A., & Savara, A. (2019) · ACS Catalysis · doi:10.1021/acscatal.9b01234 · Cited by 222
Metadata
- Authors
- Simmons, E. M., & Hartwig, J. F.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2012-03-05
- Volume
- 51
- Issue
- 13
- Pages
- 3066-3072
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W1979259658
- Cited by
- 2,136
- References
- 0
- FWCI
- 58.91
- Type
- journal article
- Language
- en
- Open access
- closed
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