The DOI matches its Crossref record; 12 of the 12 references it cites were found in a registry or an index.
Towards a Green Process for Bulk‐Scale Synthesis of Ethyl Acetate: Efficient Acceptorless Dehydrogenation of Ethanol
Abstract
Green is a go: An efficient acceptorless dehydrogenative dimerization of ethanol to give ethyl acetate was realized (see scheme). The reaction proceeds under mild reaction conditions in the presence of a ruthenium catalyst with concomitant liberation of molecular hydrogen, which can be used as a valuable product itself. At low catalyst loading (50 ppm), high yields of ethyl acetate and excellent catalyst turnover numbers are achieved.
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Citations
Cites
Ethanol for a Sustainable Energy Future
Goldemberg, J. (2007) · Science · doi:10.1126/science.1137013 · Cited by 1,423
Weissermel, K., & Arpe, H. (2003) · Wiley eBooks · doi:10.1002/9783527619191 · Cited by 1,290
Direct Synthesis of Amides from Alcohols and Amines with Liberation of H 2
Gunanathan, C., Ben-David, Y., & Milstein, D. (2007) · Science · doi:10.1126/science.1145295 · Cited by 1,288
Catalytic Hydrogenation of Carbon Dioxide Using Ir(III)−Pincer Complexes
Tanaka, R., Yamashita, M., & Nozaki, K. (2009) · Journal of the American Chemical Society · doi:10.1021/ja903574e · Cited by 902
Efficient Dehydrogenation of Formic Acid Using an Iron Catalyst
Boddien, A., Mellmann, D., Gärtner, F., Jackstell, R., Junge, H., Dyson, P. J., Laurenczy, G., Ludwig, R., & Beller, M. (2011) · Science · doi:10.1126/science.1206613 · Cited by 832
Self-citationFacile Conversion of Alcohols into Esters and Dihydrogen Catalyzed by New Ruthenium Complexes
Zhang, J., Leitus, G., Ben-David, Y., & Milstein, D. (2005) · Journal of the American Chemical Society · doi:10.1021/ja052862b · Cited by 803
Hydrogen generation from formic acid and alcohols using homogeneous catalysts
Johnson, T. C., Morris, D. J., & Wills, M. (2010) · Chem. Soc. Rev. · doi:10.1039/b904495g · Cited by 660
Amide Synthesis from Alcohols and Amines by the Extrusion of Dihydrogen
Nordstrøm, L. U., Vogt, H., & Madsen, R. (2008) · Journal of the American Chemical Society · doi:10.1021/ja808129p · Cited by 519
Milstein, D. (2010) · Topics in Catalysis · doi:10.1007/s11244-010-9523-7 · Cited by 295
Acceptorless, Neat, Ruthenium-Catalyzed Dehydrogenative Cyclization of Diols to Lactones
Zhao, J., & Hartwig, J. F. (2005) · Organometallics · doi:10.1021/om048983m · Cited by 157
Cited by
Applications of Acceptorless Dehydrogenation and Related Transformations in Chemical Synthesis
Gunanathan, C., & Milstein, D. (2013) · Science · doi:10.1126/science.1229712 · Cited by 1,542
Mellmann, D., Sponholz, P., Junge, H., & Beller, M. (2016) · Chemical Society Reviews · doi:10.1039/c5cs00618j · Cited by 872
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Metadata
- Authors
- Nielsen, M., Junge, H., Kammer, A., & Beller, M.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2012-04-19
- Volume
- 51
- Issue
- 23
- Pages
- 5711-5713
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2132287644
- Cited by
- 293
- References
- 12
- FWCI
- 15.56
- Type
- journal article
- Language
- en
- Open access
- closed
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- Nielsen, M., Junge, H., Kammer, A., & Beller, M. (2012). Towards a Green Process for Bulk‐Scale Synthesis of Ethyl Acetate: Efficient Acceptorless Dehydrogenation of Ethanol. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201200625
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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