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Luminescent Ionic Transition‐Metal Complexes for Light‐Emitting Electrochemical Cells
Abstract
Higher efficiency in the end‐use of energy requires substantial progress in lighting concepts. All the technologies under development are based on solid‐state electroluminescent materials and belong to the general area of solid‐state lighting (SSL). The two main technologies being developed in SSL are light‐emitting diodes (LEDs) and organic light‐emitting diodes (OLEDs), but in recent years, light‐emitting electrochemical cells (LECs) have emerged as an alternative option. The luminescent materials in LECs are either luminescent polymers together with ionic salts or ionic species, such as ionic transition‐metal complexes (iTMCs). Cyclometalated complexes of Ir III are by far the most utilized class of iTMCs in LECs. Herein, we show how these complexes can be prepared and discuss their unique electronic, photophysical, and photochemical properties. Finally, the progress in the performance of iTMCs based LECs, in terms of turn‐on time, stability, efficiency, and color is presented.
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Cites
The energy gap law for radiationless transitions in large molecules
Englman, R., & Jortner, J. (1970) · Molecular Physics · doi:10.1080/00268977000100171 · Cited by 2,778
Topics in Current Chemistry: Inorganic Biochemistry
(1976) · Topics in Current Chemistry · doi:10.1007/bfb0045697 · Cited by 1,044
A Major Environmental Cause of Death
Martin, W. J., Glass, R. I., Balbus, J. M., & Collins, F. S. (2011) · Science · doi:10.1126/science.1213088 · Cited by 200
Metadata
- Authors
- Costa, R. D., Ortí, E., Bolink, H. J., Monti, F., Accorsi, G., & Armaroli, N.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2012-08-06
- Volume
- 51
- Issue
- 33
- Pages
- 8178-8211
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2057830365
- Cited by
- 971
- References
- 3
- FWCI
- 49.24
- Type
- journal article
- Language
- en
- Open access
- closed
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- Costa, R. D., Ortí, E., Bolink, H. J., Monti, F., Accorsi, G., & Armaroli, N. (2012). Luminescent Ionic Transition‐Metal Complexes for Light‐Emitting Electrochemical Cells. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201201471
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