The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Metal‐free Catalytic Olefin Hydrogenation: Low‐Temperature H2 Activation by Frustrated Lewis Pairs
Abstract
Weak nucleophiles for strong activation: The reversible activation of dihydrogen by an electron-deficient phosphine, (C6F5)PPh2, in combination with the Lewis acid B(C6F5)3 at −80 °C was accomplished. The catalytic hydrogenation of olefins proceeds through protonation and subsequent hydride attack. Electron-deficient phosphines and diarlyamines were demonstrated to be viable Lewis bases for the reaction, thus allowing catalyst loadings of 10 to 5 mol %.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Effect of the damping function in dispersion corrected density functional theory
Grimme, S., Ehrlich, S., & Goerigk, L. (2011) · Journal of Computational Chemistry · doi:10.1002/jcc.21759 · Cited by 28,221
Self-citation
Metadata
- Authors
- Greb, L., Oña‐Burgos, P., Schirmer, B., Grimme, S., Stephan, D. W., & Paradies, J.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2012-08-31
- Volume
- 51
- Issue
- 40
- Pages
- 10164-10168
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2153802466
- Cited by
- 261
- References
- 1
- FWCI
- 16.62
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Metal‐free Catalytic Olefin Hydrogenation: Low‐Temperature H2 Activation by Frustrated Lewis Pairs. https://app.cochat.ai/papers/10.1002/anie.201204007
- The paper
- Greb, L., Oña‐Burgos, P., Schirmer, B., Grimme, S., Stephan, D. W., & Paradies, J. (2012). Metal‐free Catalytic Olefin Hydrogenation: Low‐Temperature H2 Activation by Frustrated Lewis Pairs. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201204007
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
