The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Conversion of a Singlet Silylene to a stable Biradical
Open accessAbstract
Silicon becomes colored: Stable biradicals were prepared from an N-heterocyclic carbene stabilized SiCl2 and a cyclic alkyl(amino)carbene, and characterized as two polymorphs. The deep-blue crystals of one polymorph are stable upon exposure to air for about a week, while the solution in THF decomposes rapidly when exposed to air. In a side reaction, the different carbene species react with each other under CH activation and CC bond formation in the presence of the biradical.
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Citations
Cites
A new mixing of Hartree–Fock and local density-functional theories
Becke, A. D. (1993) · The Journal of Chemical Physics · doi:10.1063/1.464304 · Cited by 16,515
Cited by
Cyclic (Alkyl)(Amino)Carbenes (CAACs): Stable Carbenes on the Rise
Soleilhavoup, M., & Bertrand, G. (2015) · Accounts of Chemical Research · doi:10.1021/ar5003494 · Cited by 932
All-carbon quaternary centers in natural products and medicinal chemistry: recent advances
Ling, T., & Rivas, F. (2016) · Tetrahedron · doi:10.1016/j.tet.2016.09.002 · Cited by 312
Metadata
- Authors
- Mondal, K. C., Roesky, H. W., Schwarzer, M. C., Frenking, G., Tkach, I., Wolf, H., Kratzert, D., Herbst‐Irmer, R., Niepötter, B., & Stalke, D.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2012-12-20
- Volume
- 52
- Issue
- 6
- Pages
- 1801-1805
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W1996939043
- Cited by
- 174
- References
- 1
- FWCI
- 11.54
- Type
- journal article
- Language
- en
- Open access
- green
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- Mondal, K. C., Roesky, H. W., Schwarzer, M. C., Frenking, G., Tkach, I., Wolf, H., Kratzert, D., Herbst‐Irmer, R., Niepötter, B., & Stalke, D. (2013). Conversion of a Singlet Silylene to a stable Biradical. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201204487
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
