Enhancing the Alkaline Hydrogen Evolution Reaction Activity through the Bifunctionality of Ni(OH) 2 /Metal Catalysts
Abstract
Active in alkaline environment: The activity of nickel, silver, and copper catalysts for the electrochemical transformation of water to molecular hydrogen in alkaline solutions was enhanced by modification of the metal surfaces by Ni(OH)(2) (see picture; I = current density and η = overpotential). The hydrogen evolution reaction rate on a Ni electrode modified by Ni(OH)(2) nanoclusters is about four times higher than on a bare Ni surface.
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The overpotential of the Ni-doped graphene catalyst is much lower than or comparable to the best values achieved with Pt-free monolithic catalysts.
“The overpotential of the Ni-doped graphene catalyst is much lower than or comparable to the best values achieved with Pt-free monolithic catalysts”
From Nanoporous Graphene with Single‐Atom Nickel Dopants: An Efficient and Stable Catalyst for Electrochemical Hydrogen Production (2015) · cites this paper as [17]
Highly efficient HER catalysts have a Gibbs free energy of H* adsorption close to zero.
“Highly efficient HER catalysts have a Gibbs free energy of H* adsorption, jDGH* j , close to zero”
From Nanoporous Graphene with Single‐Atom Nickel Dopants: An Efficient and Stable Catalyst for Electrochemical Hydrogen Production (2015) · cites this paper as [17]
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- Authors
- Danilovic, N., Subbaraman, R., Strmcnik, D., Chang, K., Paulikas, A. P., Stamenkovic, V. R., & Markovic, N. M.
- Affiliations
- Argonne National Laboratory (US)
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2012-11-05
- Volume
- 51
- Issue
- 50
- Pages
- 12495-12498
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2102724383
- Cited by
- 842
- References
- 0
- Citations by year
- 2026: 54 · 2025: 69 · 2024: 62 · 2023: 75 · 2022: 76 · 2021: 106 · 2020: 105 · 2019: 94 · 2018: 69 · 2017: 46 · 2016: 29 · 2015: 35 · 2014: 16 · 2013: 6
- FWCI
- 6.99
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Angewandte Chemie International Edition (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Materials Science › Materials Chemistry › Hydrogen Storage and Materials
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Keywords
- alkaline hydrogen evolution reaction, nickel hydroxide, bifunctional electrocatalysts, nanoclusters, silver catalysts, copper catalysts, overpotential, water splitting, electrocatalytic activity
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