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Total Structure and Electronic Properties of the Gold Nanocrystal Au36(SR)24
Abstract
A golden opportunity: the total structure of a Au(36)(SR)(24) nanocluster reveals an unexpected face-centered-cubic tetrahedral Au(28) kernel (magenta). The protecting layer exhibits an intriguing combination of binding modes, consisting of four regular arch-like staples and the unprecedented appearance of twelve bridging thiolates (yellow). This unique protecting network and superatom electronic shell structure confer extreme stability and robustness.
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Barnett, R. N., & Landman, U. (1993) · Physical Review B · doi:10.1103/physrevb.48.2081 · Cited by 629
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Cited by
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Yang, H., Wang, Y., Huang, H., Gell, L., Lehtovaara, L., Malola, S., Häkkinen, H., & Zheng, N. (2013) · Nature Communications · doi:10.1038/ncomms3422 · Cited by 786
Engineering ultrasmall water-soluble gold and silver nanoclusters for biomedical applications
Luo, Z., Zheng, K., & Xie, J. (2014) · Chem. Commun. · doi:10.1039/c3cc47512c · Cited by 441
Zhukhovitskiy, A. V., MacLeod, M. J., & Johnson, J. A. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00220 · Cited by 363
Luminescent Noble Metal Nanoclusters as an Emerging Optical Probe for Sensor Development
Yuan, X., Luo, Z., Yu, Y., Yao, Q., & Xie, J. (2013) · Chemistry – An Asian Journal · doi:10.1002/asia.201201236 · Cited by 328
Properties of the gold–sulphur interface: from self-assembled monolayers to clusters
Bürgi, T. (2015) · Nanoscale · doi:10.1039/c5nr03497c · Cited by 287
Metadata
- Authors
- Zeng, C., Qian, H., Li, T., Li, G., Rosi, N. L., Yoon, B., Barnett, R. N., Whetten, R. L., Landman, U., & Jin, R.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2012-11-14
- Volume
- 51
- Issue
- 52
- Pages
- 13114-13118
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2066778093
- Cited by
- 582
- References
- 1
- FWCI
- 27.95
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zeng, C., Qian, H., Li, T., Li, G., Rosi, N. L., Yoon, B., Barnett, R. N., Whetten, R. L., Landman, U., & Jin, R. (2012). Total Structure and Electronic Properties of the Gold Nanocrystal Au36(SR)24. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201207098
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