The DOI matches its Crossref record; 71 of the 71 references it cites were found in a registry or an index.
Low-transition-temperature mixtures (LTTMs): A new generation of designer solvents
Abstract
A new generation of designer solvents emerged in the last decade as promising green media for multiple applications, including separation processes: the low‐transition‐temperature mixtures (LTTMs). They can be prepared by mixing natural high‐melting‐point starting materials, which form a liquid by hydrogen‐bond interactions. Among them, deep‐eutectic solvents (DESs) were presented as promising alternatives to conventional ionic liquids (ILs). Some limitations of ILs are overcome by LTTMs, which are cheap and easy to prepare from natural and readily available starting materials, biodegradable, and renewable.
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In the citing paper
“Deep eutectic solvents (DESs) were introduced as analogues and alternative green solvents to the conventional ILs, with the advantage of easy preparation with high purities and low cost [28,29].”
From Development of hydrophobic deep eutectic solvents for extraction of pesticides from aqueous environments (2017) · cites this paper as [29]
In the citing paper
“Most of the synthesized DES reviewed [10,12,22] are hydrophilic.”
From Recent Advances in Hydrophobic Deep Eutectic Solvents for Extraction (2019) · cites this paper as [22]
In the citing paper
“Some of the underexplored fields of DES include biomass processing and liquid-liquid extractions or extractive distillation [22].”
From Recent Advances in Hydrophobic Deep Eutectic Solvents for Extraction (2019) · cites this paper as [22]
Citations
Cites
Abbott, A. P., Capper, G., Davies, D. L., Rasheed, R. K., & Tambyrajah, V. (2003) · Chemical Communications · doi:10.1039/b210714g · Cited by 5,738
Deep eutectic solvents: syntheses, properties and applications
Zhang, Q., De Oliveira Vigier, K., Royer, S., & Jérôme, F. (2012) · Chemical Society Reviews · doi:10.1039/c2cs35178a · Cited by 4,899
Abbott, A. P., Boothby, D., Capper, G., Davies, D. L., & Rasheed, R. K. (2004) · Journal of the American Chemical Society · doi:10.1021/ja048266j · Cited by 4,340
ANALYSIS OF RECENT MEASUREMENTS OF THE VISCOSITY OF GLASSES
Fulcher, G. S. (1925) · Journal of the American Ceramic Society · doi:10.1111/j.1151-2916.1925.tb16731.x · Cited by 4,199
Ionic liquids. Green solvents for the future
Earle, M. J., & Seddon, K. R. (2000) · Pure and Applied Chemistry · doi:10.1351/pac200072071391 · Cited by 2,813
Origins, Current Status, and Future Challenges of Green Chemistry
Anastas, P. T., & Kirchhoff, M. M. (2002) · Accounts of Chemical Research · doi:10.1021/ar010065m · Cited by 2,221
What is a green solvent? A comprehensive framework for the environmental assessment of solvents
Capello, C., Fischer, U., & Hungerbühler, K. (2007) · Green Chemistry · doi:10.1039/b617536h · Cited by 1,917
The properties of organic liquids that are relevant to their use as solvating solvents
Marcus, Y. (1993) · Chemical Society Reviews · doi:10.1039/cs9932200409 · Cited by 1,637
Choi, Y. H., van Spronsen, J., Dai, Y., Verberne, M., Hollmann, F., Arends, I. W. C. E., Witkamp, G.-J., & Verpoorte, R. (2011) · Plant Physiology · doi:10.1104/pp.111.178426 · Cited by 1,368
LI, C. ‐., & Chen, L. (2005) · Chemical Society Reviews · doi:10.1039/b507207g · Cited by 1,335
Research works printed but not linked: 3
- Savchenko P. S., 1959, Russ. J. Inorg. Chem., 4, 186
- R. C. Harris Physical Properties of Alcohol‐Based Deep‐Eutectic Solvents Ph.d. Thesis University of Leicester 2009.
- Feynman R. P., 1960, Eng. Sci., 23, 22
Cited by
Sorted by citations
Deep eutectic solvents: A review of fundamentals and applications
Hansen, B. B., Spittle, S., Chen, B., Poe, D., Zhang, Y., Klein, J. M., Horton, A., Adhikari, L., Zelovich, T., Doherty, B. W., et al. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00385 · Cited by 3,422
Natural Deep Eutectic Solvents – Solvents for the 21st Century
Paiva, A., Craveiro, R., Aroso, I., Martins, M., Reis, R. L., & Duarte, A. R. C. (2014) · ACS Sustainable Chemistry & Engineering · doi:10.1021/sc500096j · Cited by 2,458
The E factor 25 years on: the rise of green chemistry and sustainability
Sheldon, R. A. (2016) · Green Chemistry · doi:10.1039/c6gc02157c · Cited by 1,628
Titirici, M., White, R. J., Brun, N., Budarin, V. L., Su, D. S., del Monte, F., Clark, J. H., & MacLachlan, M. J. (2014) · Chemical Society Reviews · doi:10.1039/c4cs00232f · Cited by 1,297
Insights into the Nature of Eutectic and Deep Eutectic Mixtures
Martins, M. A. R., Pinho, S. P., & Coutinho, J. A. P. (2018) · Journal of Solution Chemistry · doi:10.1007/s10953-018-0793-1 · Cited by 1,235
Metadata
- Authors
- Francisco, M., van den Bruinhorst, A., & Kroon, M. C.
- Affiliations
- Eindhoven University of Technology (NL)
- Corresponding author
- Kroon, Maaike C.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2013-02-10
- Volume
- 52
- Issue
- 11
- Pages
- 3074-3085
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2133982938
- Cited by
- 1,378
- References
- 71
- Citations by year
- 2026: 97 · 2025: 101 · 2024: 106 · 2023: 115 · 2022: 123 · 2021: 121 · 2020: 144 · 2019: 140 · 2018: 105 · 2017: 116 · 2016: 74 · 2015: 73 · 2014: 47 · 2013: 15
- FWCI
- 27.61
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Angewandte Chemie International Edition (publishedVersion)
- PubMed (publishedVersion)
- TU/e Research Portal (submittedVersion)
- Topics
- Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Ionic liquids properties and applications
- Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Phase Equilibria and Thermodynamics
- Physical Sciences › Engineering › Mechanical Engineering › Lubricants and Their Additives
- Keywords
- low transition temperature mixtures, deep eutectic solvents, ionic liquids, hydrogen bonding, green solvents, separation processes, biodegradable solvents, renewable solvents
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