Cited by 155Supramolecular Self-Assembly in MaterialsSupramolecular Chemistry and ComplexesSurface Chemistry and Catalysis

The DOI matches its Crossref record.

Self‐Assembly of Racemic Alanine Derivatives: Unexpected Chiral Twist and Enhanced Capacity for the Discrimination of Chiral Species

Cao, Hai, Zhu, Xuefeng, Liu, Minghua·2013·Angewandte Chemie International Edition

Abstract

Twisted ribbons were formed by the self-assembly of racemic alanine derivatives (middle picture), whereas only flat nanostructures were obtained from the individual enantiomers (left). The twist was sensitive to a slight enantiomeric excess and showed remarkable macroscopic chirality. Moreover, it could discriminate various amino acid derivatives (right) and even enabled the determination of the ee value of a mixed system.

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Crossref · 10.1002/anie.201300444

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  • Synthetic polymers embedding a modestly biased racemic mixture of enantiomers adopt a single-handed helical conformation thanks to the 'majority-rules' effect.

    “synthetic polymers embedding a modestly biased racemic mixture of enantiomers adopt a single-handed helical conformation thanks to the so-called ''majority-rules'' effect.”

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Research works printed but not linked: 41

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Metadata

Authors
Cao, H., Zhu, X., & Liu, M.
Affiliations
Chinese Academy of Sciences (CN)
Corresponding author
Liu, Minghua
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2013-03-11
Volume
52
Issue
15
Pages
4122-4126
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2135533106
Cited by
155
References
0
Citations by year
2026: 4 · 2025: 6 · 2024: 8 · 2023: 1 · 2022: 10 · 2021: 11 · 2020: 10 · 2019: 10 · 2018: 8 · 2017: 15 · 2016: 18 · 2015: 19 · 2014: 31 · 2013: 4
FWCI
9.17
Type
journal article
Language
en
Open access
closed
Locations
  • Angewandte Chemie International Edition (publishedVersion)
  • PubMed (publishedVersion)
Topics
  • Physical Sciences › Materials Science › Biomaterials › Supramolecular Self-Assembly in Materials
  • Physical Sciences › Chemistry › Organic Chemistry › Supramolecular Chemistry and Complexes
  • Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Surface Chemistry and Catalysis
Keywords
self-assembly, twisted ribbons, enantiomeric excess, chiral recognition, amino acid derivatives, enantiomer separation, enantiomeric excess determination
MeSH terms
Alanine, Circular Dichroism, Stereoisomerism, Molecular Structure

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