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Exceptional Poly(acrylic acid)‐Based Artificial [FeFe]‐Hydrogenases for Photocatalytic H2 Production in Water

Wang, Feng, Liang, Wen‐Jing, Jian, Jing‐Xin, Li, Cheng‐Bo, Chen, Bin, Tung, Chen‐Ho, Wu, Li‐Zhu·2013·Angewandte Chemie International Edition

Abstract

Light, polymer, action: A set of water-soluble poly(acrylic acid) catalysts PAA-g-Fe2S2 containing {Fe2S2}, an [FeFe]-hydrogenase active-site mimic, is synthesized. This system, combined with CdSe quantum dots and ascorbic acid, has an exceptional turnover number and initial turnover frequency (27 135 and 3.6 s−1) for the photocatalytic production of H2 in water, which is the highest efficiency to date for [FeFe]-hydrogenase mimics.

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Metadata

Authors
Wang, F., Liang, W., Jian, J., Li, C., Chen, B., Tung, C., & Wu, L.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2013-06-20
Volume
52
Issue
31
Pages
8134-8138
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2163538031
Cited by
166
References
0
FWCI
5.89
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Exceptional Poly(acrylic acid)‐Based Artificial [FeFe]‐Hydrogenases for Photocatalytic H2 Production in Water. https://app.cochat.ai/papers/10.1002/anie.201303110
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Wang, F., Liang, W., Jian, J., Li, C., Chen, B., Tung, C., & Wu, L. (2013). Exceptional Poly(acrylic acid)‐Based Artificial [FeFe]‐Hydrogenases for Photocatalytic H2 Production in Water. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201303110

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