The DOI matches its Crossref record; 19 of the 19 references it cites were found in a registry or an index.
Method of Continuous Variations: Applications of Job Plots to the Study of Molecular Associations in Organometallic Chemistry
Open accessAbstract
Applications of the method of continuous variations (MCV or the Method of Job) to problems of interest to organometallic chemists are described. MCV provides qualitative and quantitative insights into the stoichiometries underlying association of m molecules of A and n molecules of B to form A m B n . Applications to complex ensembles probe associations that form metal clusters and aggregates. Job plots in which reaction rates are monitored provide relative stoichiometries in rate‐limiting transition structures. In a specialized variant, ligand‐ or solvent‐dependent reaction rates are dissected into contributions in both the ground states and transition states, which affords insights into the full reaction coordinate from a single Job plot. Gaps in the literature are identified and critiqued.
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[27] Determination of binding stoichiometry by the continuous variation method: The job plot
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Wei, S., Lu, W., Le, X., Ma, C., Lin, H., Wu, B., Zhang, J., Theato, P., & Chen, T. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201908437 · Cited by 303
Mousseau, F., Oikonomou, E. K., Baldim, V., Mornet, S., & Berret, J.-F. (2018) · Colloids and Interfaces · doi:10.3390/colloids2040050 · Cited by 10
Metadata
- Authors
- Renny, J. S., Tomasevich, L. L., Tallmadge, E. H., & Collum, D. B.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2013-10-24
- Volume
- 52
- Issue
- 46
- Pages
- 11998-12013
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2073440492
- Cited by
- 722
- References
- 19
- FWCI
- 12.20
- Type
- journal article
- Language
- en
- Open access
- green
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