The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Enantioselective Organo‐Photocatalysis Mediated by Atropisomeric Thiourea Derivatives
Abstract
Can photocatalysis be performed without electron or energy transfer? To address this, organo‐photocatalysts that are based on atropisomeric thioureas and display lower excited‐state energies than the reactive substrates have been developed. These photocatalysts were found to be efficient in promoting the [2+2] photocycloaddition of 4‐alkenyl‐substituted coumarins, which led to the corresponding products with high enantioselectivity (77–96 % ee) at low catalyst loading (1–10 mol %). The photocatalytic cycle proceeds by energy sharing via the formation of both static and dynamic complexes (exciplex formation), which is aided by hydrogen bonding.
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Prier, C. K., Rankic, D. A., & MacMillan, D. W. C. (2013) · Chemical Reviews · doi:10.1021/cr300503r · Cited by 9,590
Cited by
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Zhou, Q., Zou, Y., Lu, L., & Xiao, W. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201803102 · Cited by 1,156
Supramolecular Photochemistry as a Potential Synthetic Tool: Photocycloaddition
Ramamurthy, V., & Sivaguru, J. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00040 · Cited by 459
Self-citationEnantioselective photochemistry through Lewis acid–catalyzed triplet energy transfer
Blum, T. R., Miller, Z. D., Bates, D. M., Guzei, I. A., & Yoon, T. P. (2016) · Science · doi:10.1126/science.aai8228 · Cited by 420
Chiral Photocatalyst Structures in Asymmetric Photochemical Synthesis
Genzink, M. J., Kidd, J. B., Swords, W. B., & Yoon, T. P. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00467 · Cited by 420
Asymmetric catalysis activated by visible light
Meggers, E. (2015) · Chemical Communications · doi:10.1039/c4cc09268f · Cited by 373
Metadata
- Authors
- Vallavoju, N., Selvakumar, S., Jockusch, S., Sibi, M. P., & Sivaguru, J.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2014-04-16
- Volume
- 53
- Issue
- 22
- Pages
- 5604-5608
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2170312411
- Cited by
- 181
- References
- 1
- FWCI
- 10.12
- Type
- journal article
- Language
- en
- Open access
- closed
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- Vallavoju, N., Selvakumar, S., Jockusch, S., Sibi, M. P., & Sivaguru, J. (2014). Enantioselective Organo‐Photocatalysis Mediated by Atropisomeric Thiourea Derivatives. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201310940
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