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Podlike N‐Doped Carbon Nanotubes Encapsulating FeNi Alloy Nanoparticles: High‐Performance Counter Electrode Materials for Dye‐Sensitized Solar Cells

Zheng, Xiaojia, Deng, Jiao, Wang, Nan, Deng, Dehui, Zhang, Wen‐Hua, Bao, Xinhe, Li, Can·2014·Angewandte Chemie International Edition

Abstract

Podlike nitrogen‐doped carbon nanotubes encapsulating FeNi alloy nanoparticles (Pod(N)‐FeNi) were prepared by the direct pyrolysis of organometallic precursors. Cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and Tafel polarization measurements revealed their excellent electrocatalytic activities in the I−/I 3− redox reaction of dye‐sensitized solar cells (DSSCs). This is suggested to arise from the modification of the surface electronic properties of the carbon by the encapsulated metal alloy nanoparticles (NPs). Sequential scanning with EIS and CV further showed the high electrochemical stability of the Pod(N)‐FeNi composite. DSSCs with Pod(N)‐FeNi as the counter electrode (CE) presented a power conversion efficiency of 8.82 %, which is superior to that of the control device with sputtered Pt as the CE. The Pod(N)‐FeNi composite thus shows promise as an environmentally friendly, low‐cost, and highly efficient CE material for DSSCs.

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Metadata

Authors
Zheng, X., Deng, J., Wang, N., Deng, D., Zhang, W., Bao, X., & Li, C.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2014-05-06
Volume
53
Issue
27
Pages
7023-7027
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2112641079
Cited by
344
References
2
FWCI
16.37
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Podlike N‐Doped Carbon Nanotubes Encapsulating FeNi Alloy Nanoparticles: High‐Performance Counter Electrode Materials for Dye‐Sensitized Solar Cells. https://app.cochat.ai/papers/10.1002/anie.201400388
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Zheng, X., Deng, J., Wang, N., Deng, D., Zhang, W., Bao, X., & Li, C. (2014). Podlike N‐Doped Carbon Nanotubes Encapsulating FeNi Alloy Nanoparticles: High‐Performance Counter Electrode Materials for Dye‐Sensitized Solar Cells. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201400388

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