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Controlled Synthesis of Conjugated Microporous Polymer Films: Versatile Platforms for Highly Sensitive and Label‐Free Chemo‐ and Biosensing
Abstract
Conjugated microporous polymers (CMPs), in which rigid building blocks form robust networks, are usually synthesized as insoluble and unprocessable powders. We developed a methodology using electropolymerization for the synthesis of thin CMP films. The thickness of these films is synthetically controllable, ranging from nanometers to micrometers, and they are obtained on substrates or as freestanding films. The CMP films combine a number of striking physical properties, including high porosity, extended π conjugation, facilitated exciton delocalization, and high‐rate electron transfer. We explored the CMP films as versatile platforms for highly sensitive and label‐free chemo‐ and biosensing of electron‐rich and electron‐poor arenes, metal ions, dopamine, and hypochloroic acid, featuring rapid response, excellent selectivity, and robust reusability.
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In-Vivo Electrochemistry: What Can We Learn about Living Systems?
Wilson, G. S., & Johnson, M. A. (2008) · Chemical Reviews · doi:10.1021/cr068082i · Cited by 178
Cited by
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Xie, W., Cui, D., Zhang, S.-R., Xu, Y.-H., & Jiang, D.-L. (2019) · Materials Horizons · doi:10.1039/c8mh01656a · Cited by 622
Self-citationPorous Polymers as Multifunctional Material Platforms toward Task‐Specific Applications
Wu, J., Xu, F., Li, S., Ma, P., Zhang, X., Liu, Q., Fu, R., & Wu, D. (2019) · Advanced Materials · doi:10.1002/adma.201802922 · Cited by 555
Self-citationPorous organic polymers: a promising platform for efficient photocatalysis
Zhang, T., Xing, G., Chen, W., & Chen, L. (2020) · Materials Chemistry Frontiers · doi:10.1039/c9qm00633h · Cited by 420
Porous organic polymers as a platform for sensing applications
Wang, S., Li, H., Huang, H., Cao, X., Chen, X., & Cao, D. (2022) · Chemical Society Reviews · doi:10.1039/d2cs00059h · Cited by 363
Conjugated porous polymers: incredibly versatile materials with far-reaching applications
Taylor, D., Dalgarno, S. J., Xu, Z., & Vilela, F. (2020) · Chemical Society Reviews · doi:10.1039/c9cs00315k · Cited by 259
Metadata
- Authors
- Gu, C., Huang, N., Gao, J., Xu, F., Xu, Y., & Jiang, D.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2014-04
- Volume
- 53
- Issue
- 19
- Pages
- 4850-4855
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2145592218
- Cited by
- 295
- References
- 1
- FWCI
- 17.87
- Type
- journal article
- Language
- en
- Open access
- closed
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- Gu, C., Huang, N., Gao, J., Xu, F., Xu, Y., & Jiang, D. (2014). Controlled Synthesis of Conjugated Microporous Polymer Films: Versatile Platforms for Highly Sensitive and Label‐Free Chemo‐ and Biosensing. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201402141
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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