The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Visible‐Light‐Induced Photoredox Catalysis with a Tetracerium‐Containing Silicotungstate
Abstract
The development of visible‐light‐induced photocatalysts for chemoselective functional group transformations has received considerable attention. Polyoxometalates (POMs) are potential materials for efficient photocatalysts because their properties can be precisely tuned by changing their constituent elements and structures and by the introduction of additional metal cations. Furthermore, they are thermally and oxidatively more stable than the frequently utilized organometallic complexes. The visible‐light‐responsive tetranuclear cerium(III)‐containing silicotungstate TBA 6[{Ce(H 2 O)}2{Ce(CH 3 CN)}2(μ 4‐O)(γ‐SiW 10 O 36)2] (CePOM; TBA=tetra‐n‐butylammonium) has now been synthesized; when CePOM was irradiated with visible light (λ>400 nm), a unique intramolecular Ce III‐to‐POM(W VI) charge transfer was observed. With CePOM, the photocatalytic oxidative dehydrogenation of primary and secondary amines as well as the α‐cyanation of tertiary amines smoothly proceeded in the presence of O 2 (1 atm) as the sole oxidant.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Prier, C. K., Rankic, D. A., & MacMillan, D. W. C. (2013) · Chemical Reviews · doi:10.1021/cr300503r · Cited by 9,590
Cited by
Zhang, H., Liu, W., Li, A., Zhang, D., Li, X., Zhai, F., Chen, L., Chen, L., Wang, Y., & Wang, S. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201909718 · Cited by 485
Qiao, Y., & Schelter, E. J. (2018) · Accounts of Chemical Research · doi:10.1021/acs.accounts.8b00336 · Cited by 281
Polyoxometalate@Metal–Organic Framework Composites as Effective Photocatalysts
Liu, Y., Tang, C., Cheng, M., Chen, M., Chen, S., Lei, L., Chen, Y., Yi, H., Fu, Y., & Li, L. (2021) · ACS Catalysis · doi:10.1021/acscatal.1c03866 · Cited by 253
Metadata
- Authors
- Suzuki, K., Tang, F., Kikukawa, Y., Yamaguchi, K., & Mizuno, N.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2014-04-16
- Volume
- 53
- Issue
- 21
- Pages
- 5356-5360
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2098089756
- Cited by
- 159
- References
- 1
- FWCI
- 8.19
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Visible‐Light‐Induced Photoredox Catalysis with a Tetracerium‐Containing Silicotungstate. https://app.cochat.ai/papers/10.1002/anie.201403215
- The paper
- Suzuki, K., Tang, F., Kikukawa, Y., Yamaguchi, K., & Mizuno, N. (2014). Visible‐Light‐Induced Photoredox Catalysis with a Tetracerium‐Containing Silicotungstate. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201403215
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
