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[2+2] Cycloaddition of 1,3‐Dienes by Visible Light Photocatalysis
Open accessAbstract
[2+2] Photocycloadditions of 1,3‐dienes represent a powerful yet synthetically underutilized class of reactions. We report that visible light absorbing transition metal complexes enable the [2+2] cycloaddition of a diverse range of 1,3‐dienes. The ability to use long‐wavelength visible light is attractive because these reaction conditions tolerate the presence of sensitive functional groups that might be readily decomposed by the high‐energy UVC radiation required for direct photoexcitation of 1,3‐dienes. The resulting vinylcyclobutane products are poised for a variety of further diversification reactions, and this method is consequently expected to be powerfully enabling in the synthesis of complex organic targets.
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Prier, C. K., Rankic, D. A., & MacMillan, D. W. C. (2013) · Chemical Reviews · doi:10.1021/cr300503r · Cited by 9,590
Cited by
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Strieth-Kalthoff, F., & Glorius, F. (2020) · Chem · doi:10.1016/j.chempr.2020.07.010 · Cited by 650
Zhu, M., Zheng, C., Zhang, X., & You, S.-L. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.8b12965 · Cited by 298
Metadata
- Authors
- Hurtley, A. E., Lu, Z., & Yoon, T. P.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2014-07
- Volume
- 53
- Issue
- 34
- Pages
- 8991-8994
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2146410562
- Cited by
- 182
- References
- 1
- FWCI
- 7.08
- Type
- journal article
- Language
- en
- Open access
- green
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- CoChat. (2026). Citation check: [2+2] Cycloaddition of 1,3‐Dienes by Visible Light Photocatalysis. https://app.cochat.ai/papers/10.1002/anie.201405359
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- Hurtley, A. E., Lu, Z., & Yoon, T. P. (2014). [2+2] Cycloaddition of 1,3‐Dienes by Visible Light Photocatalysis. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201405359
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