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Using Surface Segregation To Design Stable Ru‐Ir Oxides for the Oxygen Evolution Reaction in Acidic Environments
Abstract
The methods used to improve catalytic activity are well‐established, however elucidating the factors that simultaneously control activity and stability is still lacking, especially for oxygen evolution reaction (OER) catalysts. Here, by studying fundamental links between the activity and stability of well‐characterized monometallic and bimetallic oxides, we found that there is generally an inverse relationship between activity and stability. To overcome this limitation, we developed a new synthesis strategy that is based on tuning the near‐surface composition of Ru and Ir elements by surface segregation, thereby resulting in the formation of a nanosegregated domain that balances the stability and activity of surface atoms. We demonstrate that a Ru 0.5 Ir 0.5 alloy synthesized by using this method exhibits four‐times higher stability than the best Ru‐Ir oxygen evolution reaction materials, while still preserving the same activity.
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Cites
Armand, M., & Tarascon, J.-M. (2008) · Nature · doi:10.1038/451652a · Cited by 19,612
Cited by
Reier, T., Nong, H. N., Teschner, D., Schlögl, R., & Strasser, P. (2017) · Advanced Energy Materials · doi:10.1002/aenm.201601275 · Cited by 1,253
Bifunctional Electrocatalysts for Overall and Hybrid Water Splitting
Quan, L., Jiang, H., Mei, G., Sun, Y., & You, B. (2024) · Chemical Reviews · doi:10.1021/acs.chemrev.3c00332 · Cited by 874
Oh, H.-S., Nong, H. N., Reier, T., Bergmann, A., Gliech, M., Ferreira de Araújo, J., Willinger, E., Schlögl, R., Teschner, D., & Strasser, P. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b07199 · Cited by 641
Stability of electrocatalytic OER: from principle to application
Li, H., Lin, Y., Duan, J., Wen, Q., Liu, Y., & Zhai, T. (2024) · Chemical Society Reviews · doi:10.1039/d3cs00010a · Cited by 540
Porous cobalt oxide nanoplates enriched with oxygen vacancies for oxygen evolution reaction
Xu, W., Lyu, F., Bai, Y., Gao, A., Feng, J., Cai, Z., & Yin, Y. (2018) · Nano Energy · doi:10.1016/j.nanoen.2017.11.022 · Cited by 513
Metadata
- Authors
- Danilovic, N., Subbaraman, R., Chang, K. C., Chang, S. H., Kang, Y., Snyder, J., Paulikas, A. P., Strmcnik, D., Kim, Y. T., Myers, D., Stamenkovic, V. R., & Markovic, N. M.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2014-10-08
- Volume
- 53
- Issue
- 51
- Pages
- 14016-14021
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2007772808
- Cited by
- 418
- References
- 1
- FWCI
- 8.08
- Type
- journal article
- Language
- en
- Open access
- closed
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- The paper
- Danilovic, N., Subbaraman, R., Chang, K. C., Chang, S. H., Kang, Y., Snyder, J., Paulikas, A. P., Strmcnik, D., Kim, Y. T., Myers, D., Stamenkovic, V. R., & Markovic, N. M. (2014). Using Surface Segregation To Design Stable Ru‐Ir Oxides for the Oxygen Evolution Reaction in Acidic Environments. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201406455
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