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Cited by 418

The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.

Using Surface Segregation To Design Stable Ru‐Ir Oxides for the Oxygen Evolution Reaction in Acidic Environments

Danilovic, Nemanja, Subbaraman, Ramachandran, Chang, Kee Chul, Chang, Seo Hyoung, Kang, Yijin, Snyder, Joshua, Paulikas, Arvydas Paul, Strmcnik, Dusan, Kim, Yong Tae, Myers, Deborah, Stamenkovic, Vojislav R., Markovic, Nenad M.·2014·Angewandte Chemie International Edition

Abstract

The methods used to improve catalytic activity are well‐established, however elucidating the factors that simultaneously control activity and stability is still lacking, especially for oxygen evolution reaction (OER) catalysts. Here, by studying fundamental links between the activity and stability of well‐characterized monometallic and bimetallic oxides, we found that there is generally an inverse relationship between activity and stability. To overcome this limitation, we developed a new synthesis strategy that is based on tuning the near‐surface composition of Ru and Ir elements by surface segregation, thereby resulting in the formation of a nanosegregated domain that balances the stability and activity of surface atoms. We demonstrate that a Ru 0.5 Ir 0.5 alloy synthesized by using this method exhibits four‐times higher stability than the best Ru‐Ir oxygen evolution reaction materials, while still preserving the same activity.

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Metadata

Authors
Danilovic, N., Subbaraman, R., Chang, K. C., Chang, S. H., Kang, Y., Snyder, J., Paulikas, A. P., Strmcnik, D., Kim, Y. T., Myers, D., Stamenkovic, V. R., & Markovic, N. M.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2014-10-08
Volume
53
Issue
51
Pages
14016-14021
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2007772808
Cited by
418
References
1
FWCI
8.08
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Using Surface Segregation To Design Stable Ru‐Ir Oxides for the Oxygen Evolution Reaction in Acidic Environments. https://app.cochat.ai/papers/10.1002/anie.201406455
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Danilovic, N., Subbaraman, R., Chang, K. C., Chang, S. H., Kang, Y., Snyder, J., Paulikas, A. P., Strmcnik, D., Kim, Y. T., Myers, D., Stamenkovic, V. R., & Markovic, N. M. (2014). Using Surface Segregation To Design Stable Ru‐Ir Oxides for the Oxygen Evolution Reaction in Acidic Environments. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201406455

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