The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Sunlight‐Driven Hydrogen Peroxide Production from Water and Molecular Oxygen by Metal‐Free Photocatalysts
Abstract
Design of green, safe, and sustainable process for the synthesis of hydrogen peroxide (H 2 O 2) is a very important subject. Early reported processes, however, require hydrogen (H 2) and palladium‐based catalysts. Herein we propose a photocatalytic process for H 2 O 2 synthesis driven by metal‐free catalysts with earth‐abundant water and molecular oxygen (O 2) as resources under sunlight irradiation (λ>400 nm). We use graphitic carbon nitride (g‐C 3 N 4) containing electron‐deficient aromatic diimide units as catalysts. Incorporating the diimide units positively shifts the valence‐band potential of the catalysts, while maintaining sufficient conduction‐band potential for O 2 reduction. Visible light irradiation of the catalysts in pure water with O 2 successfully produces H 2 O 2 by oxidation of water by the photoformed valence‐band holes and selective two‐electron reduction of O 2 by the conduction band electrons.
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Cites
Cui, Y., Ding, Z., Liu, P., Antonietti, M., Fu, X., & Wang, X. (2012) · Phys. Chem. Chem. Phys. · doi:10.1039/c1cp22820j · Cited by 585
Cited by
Ong, W.-J., Tan, L.-L., Ng, Y. H., Yong, S.-T., & Chai, S.-P. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00075 · Cited by 7,147
Spontaneous Generation of Hydrogen Peroxide from Aqueous Microdroplets
Lee, J. K., Walker, K. L., Han, H. S., Kang, J., Prinz, F. B., Waymouth, R. M., Nam, H. G., & Zare, R. N. (2019) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1911883116 · Cited by 717
Kofuji, Y., Isobe, Y., Shiraishi, Y., Sakamoto, H., Tanaka, S., Ichikawa, S., & Hirai, T. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b05806 · Cited by 587
Self-citationZeng, X., Liu, Y., Kang, Y., Li, Q., Xia, Y., Zhu, Y., Hou, H., Uddin, M. H., Gengenbach, T. R., Xia, D., et al. (2020) · ACS Catalysis · doi:10.1021/acscatal.9b05247 · Cited by 482
Zheng, Q., Durkin, D. P., Elenewski, J. E., Sun, Y., Banek, N. A., Hua, L., Chen, H., Wagner, M. J., Zhang, W., & Shuai, D. (2016) · Environmental Science & Technology · doi:10.1021/acs.est.6b02579 · Cited by 328
Metadata
- Authors
- Shiraishi, Y., Kanazawa, S., Kofuji, Y., Sakamoto, H., Ichikawa, S., Tanaka, S., & Hirai, T.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2014-10-07
- Volume
- 53
- Issue
- 49
- Pages
- 13454-13459
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2164440612
- Cited by
- 649
- References
- 1
- FWCI
- 8.62
- Type
- journal article
- Language
- en
- Open access
- closed
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- Shiraishi, Y., Kanazawa, S., Kofuji, Y., Sakamoto, H., Ichikawa, S., Tanaka, S., & Hirai, T. (2014). Sunlight‐Driven Hydrogen Peroxide Production from Water and Molecular Oxygen by Metal‐Free Photocatalysts. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201407938
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