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SrNb0.1Co0.7Fe0.2O3−δ Perovskite as a Next‐Generation Electrocatalyst for Oxygen Evolution in Alkaline Solution
Abstract
The perovskite SrNb 0.1 Co 0.7 Fe 0.2 O 3−δ (SNCF) is a promising OER electrocatalyst for the oxygen evolution reaction (OER), with remarkable activity and stability in alkaline solutions. This catalyst exhibits a higher intrinsic OER activity, a smaller Tafel slope and better stability than the state‐of‐the‐art precious‐metal IrO 2 catalyst and the well‐known BSCF perovskite. The mass activity and stability are further improved by ball milling. Several factors including the optimized e g orbital filling, good ionic and charge transfer abilities, as well as high OH− adsorption and O 2 desorption capabilities possibly contribute to the excellent OER activity.
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Opportunities and challenges for a sustainable energy future
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Benchmarking Heterogeneous Electrocatalysts for the Oxygen Evolution Reaction
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The Mechanism of Water Oxidation: From Electrolysis via Homogeneous to Biological Catalysis
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Cited by
Chatenet, M., Pollet, B. G., Dekel, D. R., Dionigi, F., Deseure, J., Millet, P., Braatz, R. D., Bazant, M. Z., Eikerling, M., Staffell, I., et al. (2022) · Chemical Society Reviews · doi:10.1039/d0cs01079k · Cited by 2,025
Transition‐Metal (Co, Ni, and Fe)‐Based Electrocatalysts for the Water Oxidation Reaction
Han, L., Dong, S., & Wang, E. (2016) · Advanced Materials · doi:10.1002/adma.201602270 · Cited by 1,769
Tang, T., Jiang, W.-J., Niu, S., Liu, N., Luo, H., Chen, Y.-Y., Jin, S.-F., Gao, F., Wan, L.-J., & Hu, J.-S. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b03507 · Cited by 880
Self-citationPorous cobalt oxide nanoplates enriched with oxygen vacancies for oxygen evolution reaction
Xu, W., Lyu, F., Bai, Y., Gao, A., Feng, J., Cai, Z., & Yin, Y. (2018) · Nano Energy · doi:10.1016/j.nanoen.2017.11.022 · Cited by 513
Ďurovič, M., Hnát, J., & Bouzek, K. (2021) · Journal of Power Sources · doi:10.1016/j.jpowsour.2021.229708 · Cited by 436
Metadata
- Authors
- Zhu, Y., Zhou, W., Chen, Z., Chen, Y., Su, C., Tadé, M. O., & Shao, Z.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2015-02-04
- Volume
- 54
- Issue
- 13
- Pages
- 3897-3901
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2112320230
- Cited by
- 463
- References
- 6
- FWCI
- 17.79
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zhu, Y., Zhou, W., Chen, Z., Chen, Y., Su, C., Tadé, M. O., & Shao, Z. (2015). SrNb0.1Co0.7Fe0.2O3−δ Perovskite as a Next‐Generation Electrocatalyst for Oxygen Evolution in Alkaline Solution. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201408998
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