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Spatial Structuring of a Supramolecular Hydrogel by using a Visible‐Light Triggered Catalyst
Abstract
Spatial control over the self‐assembly of synthetic molecular fibers through the use of light‐switchable catalysts can lead to the controlled formation of micropatterns made up of hydrogel structures. A photochromic switch, capable of reversibly releasing a proton upon irradiation, can act as a catalyst for in situ chemical bond formation between otherwise soluble building blocks, thereby leading to fiber formation and gelation in water. The use of a photoswitchable catalyst allows control over the distribution as well as the mechanical properties of the hydrogel material. By using homemade photomasks, spatially structured hydrogels were formed starting from bulk solutions of small molecule gelator precursors through light‐triggered local catalyst activation.
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Cited by
Light-controlled self-assembly of non-photoresponsive nanoparticles
Kundu, P. K., Samanta, D., Leizrowice, R., Margulis, B., Zhao, H., Börner, M., Udayabhaskararao, T., Manna, D., & Klajn, R. (2015) · Nature Chemistry · doi:10.1038/nchem.2303 · Cited by 543
Gels with sense: supramolecular materials that respond to heat, light and sound
Jones, C. D., & Steed, J. W. (2016) · Chemical Society Reviews · doi:10.1039/c6cs00435k · Cited by 487
Metadata
- Authors
- Maity, C., Hendriksen, W. E., van Esch, J. H., & Eelkema, R.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2014-11-10
- Volume
- 54
- Issue
- 3
- Pages
- 998-1001
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2169015250
- Cited by
- 163
- References
- 0
- FWCI
- 6.65
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Spatial Structuring of a Supramolecular Hydrogel by using a Visible‐Light Triggered Catalyst. https://app.cochat.ai/papers/10.1002/anie.201409198
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- Maity, C., Hendriksen, W. E., van Esch, J. H., & Eelkema, R. (2015). Spatial Structuring of a Supramolecular Hydrogel by using a Visible‐Light Triggered Catalyst. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201409198
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.