The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Photoliquefiable Ionic Crystals: A Phase Crossover Approach for Photon Energy Storage Materials with Functional Multiplicity
Abstract
Ionic crystals (ICs) of the azobenzene derivatives show photoinduced IC–ionic liquid (IL) phase transition (photoliquefaction) upon UV‐irradiation, and the resulting cis‐azobenzene ILs are reversibly photocrystallized by illumination with visible light. The photoliquefaction of ICs is accompanied by a significant increase in ionic conductivity at ambient temperature. The photoliquefaction also brings the azobenzene ICs further significance as photon energy storage materials. The cis‐IL shows thermally induced crystallization to the trans‐IC phase. This transition is accompanied by exothermic peaks with a total ΔH of 97.1 kJ mol−1, which is almost double the conformational energy stored in cis‐azobenzene chromophores. Thus, the integration of photoresponsive ILs and self‐assembly pushes the limit of solar thermal batteries.
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H. Davis, J. (2004) · Chemistry Letters · doi:10.1246/cl.2004.1072 · Cited by 1,053
Cited by
Azobenzene-based solar thermal fuels: design, properties, and applications
Dong, L., Feng, Y., Wang, L., & Feng, W. (2018) · Chemical Society Reviews · doi:10.1039/c8cs00470f · Cited by 474
Metadata
- Authors
- Ishiba, K., Morikawa, M., Chikara, C., Yamada, T., Iwase, K., Kawakita, M., & Kimizuka, N.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2014-12-05
- Volume
- 54
- Issue
- 5
- Pages
- 1532-1536
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2143780909
- Cited by
- 192
- References
- 1
- FWCI
- 3.82
- Type
- journal article
- Language
- en
- Open access
- closed
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- Ishiba, K., Morikawa, M., Chikara, C., Yamada, T., Iwase, K., Kawakita, M., & Kimizuka, N. (2015). Photoliquefiable Ionic Crystals: A Phase Crossover Approach for Photon Energy Storage Materials with Functional Multiplicity. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201410184
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