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Cited by 613

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Visible‐Light‐Driven CO2 Reduction with Carbon Nitride: Enhancing the Activity of Ruthenium Catalysts

Kuriki, Ryo, Sekizawa, Keita, Ishitani, Osamu, Maeda, Kazuhiko·2015·Angewandte Chemie International Edition

Abstract

A heterogeneous photocatalyst system that consists of a ruthenium complex and carbon nitride (C 3 N 4), which act as the catalytic and light‐harvesting units, respectively, was developed for the reduction of CO 2 into formic acid. Promoting the injection of electrons from C 3 N 4 into the ruthenium unit as well as strengthening the electronic interactions between the two units enhanced its activity. The use of a suitable solvent further improved the performance, resulting in a turnover number of greater than 1000 and an apparent quantum yield of 5.7 % at 400 nm. These are the best values that have been reported for heterogeneous photocatalysts for CO 2 reduction under visible‐light irradiation to date.

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Metadata

Authors
Kuriki, R., Sekizawa, K., Ishitani, O., & Maeda, K.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2015-01-07
Volume
54
Issue
8
Pages
2406-2409
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2095814999
Cited by
613
References
1
FWCI
24.24
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Visible‐Light‐Driven CO2 Reduction with Carbon Nitride: Enhancing the Activity of Ruthenium Catalysts. https://app.cochat.ai/papers/10.1002/anie.201411170
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Kuriki, R., Sekizawa, K., Ishitani, O., & Maeda, K. (2015). Visible‐Light‐Driven CO2 Reduction with Carbon Nitride: Enhancing the Activity of Ruthenium Catalysts. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201411170

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