The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Photoinduced Postsynthetic Polymerization of a Metal–Organic Framework toward a Flexible Stand‐Alone Membrane
Abstract
Metal–organic frameworks (MOFs) are a promising class of nanoporous polymeric materials. However, the processing of such fragile crystalline powders into desired shapes for further applications is often difficult. A photoinduced postsynthetic polymerization (PSP) strategy was now employed to covalently link MOF crystals by flexible polymer chains, thus endowing the MOF powders with processability and flexibility. Nanosized UiO‐66‐NH 2 was first functionalized with polymerizable functional groups, and its subsequent copolymerization with monomers was easily induced by UV light under solvent‐free and mild conditions. Because of the improved interaction between MOF particles and polymer chains, the resulting stand‐alone and elastic MOF‐based PSP‐derived membranes possess crack‐free and uniform structures and outstanding separation capabilities for Cr VI ions from water.
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Cites
Metal-organic framework materials as catalysts
Lee, J., Farha, O. K., Roberts, J., Scheidt, K. A., Nguyen, S. T., & Hupp, J. T. (2009) · Chemical Society Reviews · doi:10.1039/b807080f · Cited by 7,969
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Metal–organic frameworks for membrane-based separations
Denny, M. S., Moreton, J. C., Benz, L., & Cohen, S. M. (2016) · Nature Reviews Materials · doi:10.1038/natrevmats.2016.78 · Cited by 820
Wang, H., Zeng, Z., Xu, P., Li, L., Zeng, G., Xiao, R., Tang, Z., Huang, D., Tang, L., Lai, C., et al. (2019) · Chemical Society Reviews · doi:10.1039/c8cs00376a · Cited by 804
Metadata
- Authors
- Zhang, Y., Feng, X., Li, H., Chen, Y., Zhao, J., Wang, S., Wang, L., & Wang, B.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2015-03-03
- Volume
- 54
- Issue
- 14
- Pages
- 4259-4263
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W1977635285
- Cited by
- 295
- References
- 1
- FWCI
- 10.77
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zhang, Y., Feng, X., Li, H., Chen, Y., Zhao, J., Wang, S., Wang, L., & Wang, B. (2015). Photoinduced Postsynthetic Polymerization of a Metal–Organic Framework toward a Flexible Stand‐Alone Membrane. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201500207
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