The DOI matches its Crossref record; 38 of the 38 references it cites were found in a registry or an index.
Formation of Nickel Sulfide Nanoframes from Metal–Organic Frameworks with Enhanced Pseudocapacitive and Electrocatalytic Properties
Abstract
Nanoframe‐like hollow structures with unique three‐dimensional (3D) open architecture hold great promise for various applications. Current research efforts mainly focus on frame‐like noble metals and metal oxides. However, metal sulfides with frame‐like nanostructures have been rarely reported. Starting from metal–organic frameworks (MOFs), we demonstrate a novel structure‐induced anisotropic chemical etching/anion exchange method to transform Ni‐Co Prussian blue analogue (PBA) nanocubes into NiS nanoframes with tunable size. The reaction between Ni‐Co PBA nanocube templates and Na 2 S in solution leads to the formation of well‐defined NiS nanoframes. The different reactivity between the edges and the plane surface of the Ni‐Co PBA nanocubes is found to be the key factor for the formation of NiS nanoframes. Benefitting from their structural merits including 3D open structure, small size of primary nanoparticles, high specific surface area, and good structural robustness, the as‐derived NiS nanoframes manifest excellent electrochemical performance for electrochemical capacitors and hydrogen evolution reaction in alkaline electrolyte.
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Cites
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Self-citationHighly Crystalline Multimetallic Nanoframes with Three-Dimensional Electrocatalytic Surfaces
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Self-citationFabrication and application of inorganic hollow spheres
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Cited by
Metal Sulfide Hollow Nanostructures for Electrochemical Energy Storage
Yu, X., Yu, L., & Lou, X. W. (. (2016) · Advanced Energy Materials · doi:10.1002/aenm.201501333 · Cited by 760
Self-citationHan, L., Yu, X., & Lou, X. W. (. (2016) · Advanced Materials · doi:10.1002/adma.201506315 · Cited by 633
Self-citationYou, B., Jiang, N., Sheng, M., Gul, S., Yano, J., & Sun, Y. (2015) · Chemistry of Materials · doi:10.1021/acs.chemmater.5b02877 · Cited by 631
Wang, A.-L., Xu, H., & Li, G.-R. (2016) · ACS Energy Letters · doi:10.1021/acsenergylett.6b00219 · Cited by 426
Zhao, S.-N., Song, X.-Z., Song, S.-Y., & Zhang, H.-J. (2017) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2017.02.010 · Cited by 336
Metadata
- Authors
- Yu, X., Yu, L., Wu, H. B., & Lou, X. W. (.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2015-02-20
- Volume
- 54
- Issue
- 18
- Pages
- 5331-5335
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2152064334
- Cited by
- 513
- References
- 38
- FWCI
- 24.52
- Type
- journal article
- Language
- en
- Open access
- closed
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- Yu, X., Yu, L., Wu, H. B., & Lou, X. W. (. (2015). Formation of Nickel Sulfide Nanoframes from Metal–Organic Frameworks with Enhanced Pseudocapacitive and Electrocatalytic Properties. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201500267
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