The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Merging Photoredox and Nickel Catalysis: The Direct Synthesis of Ketones by the Decarboxylative Arylation of α‐Oxo Acids
Open accessAbstract
The direct decarboxylative arylation of α‐oxo acids has been achieved by synergistic visible‐light‐mediated photoredox and nickel catalysis. This method offers rapid entry to aryl and alkyl ketone architectures from simple α‐oxo acid precursors via an acyl radical intermediate. Significant substrate scope is observed with respect to both the oxo acid and arene coupling partners. This mild decarboxylative arylation can also be utilized to efficiently access medicinal agents, as demonstrated by the rapid synthesis of fenofibrate.
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Citations
Cites
Prier, C. K., Rankic, D. A., & MacMillan, D. W. C. (2013) · Chemical Reviews · doi:10.1021/cr300503r · Cited by 9,590
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Douglas, J. J., Sevrin, M. J., & Stephenson, C. R. J. (2016) · Organic Process Research & Development · doi:10.1021/acs.oprd.6b00125 · Cited by 361
Metadata
- Authors
- Chu, L., Lipshultz, J. M., & MacMillan, D. W. C.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2015-05-26
- Volume
- 54
- Issue
- 27
- Pages
- 7929-7933
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2171698115
- Cited by
- 333
- References
- 1
- FWCI
- 20.23
- Type
- journal article
- Language
- en
- Open access
- green
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- Chu, L., Lipshultz, J. M., & MacMillan, D. W. C. (2015). Merging Photoredox and Nickel Catalysis: The Direct Synthesis of Ketones by the Decarboxylative Arylation of α‐Oxo Acids. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201501908
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