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Cited by 260

The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.

Selective Dissolution of A‐Site Cations in ABO3 Perovskites: A New Path to High‐Performance Catalysts

Si, Wenzhe, Wang, Yu, Peng, Yue, Li, Junhua·2015·Angewandte Chemie International Edition

Abstract

Selective dissolution is a common corrosion process in dealloying in which an alloy is immersed in acid to remove the active element, leaving behind an inert constituent. We introduce this technique into the treatment of oxide catalysts. A three‐dimensionally ordered macroporous LaMnO 3 perovskite has been prepared and treated with diluted HNO 3 to selectively remove La cations, acquiring a novel γ‐MnO 2‐like material. LaMnO 3 is not a satisfactory catalyst on CO oxidation. Upon the removal of La cations, the obtained sample showed a significantly higher CO oxidation catalytic activity (T50=89 °C) than the initial precursor LaMnO 3 (T50=237 °C) and ordinary γ‐MnO 2 (T50=148 °C). A large surface area, a high degree of mesoporosity, excellent low‐temperature reducibility, and especially improved surface oxygen species are deduced to be responsible for CO oxidation at lower temperatures.

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Metadata

Authors
Si, W., Wang, Y., Peng, Y., & Li, J.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2015-05-12
Volume
54
Issue
27
Pages
7954-7957
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2112860211
Cited by
260
References
1
FWCI
6.53
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Selective Dissolution of A‐Site Cations in ABO3 Perovskites: A New Path to High‐Performance Catalysts. https://app.cochat.ai/papers/10.1002/anie.201502632
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Si, W., Wang, Y., Peng, Y., & Li, J. (2015). Selective Dissolution of A‐Site Cations in ABO3 Perovskites: A New Path to High‐Performance Catalysts. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201502632

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