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Selective Dissolution of A‐Site Cations in ABO3 Perovskites: A New Path to High‐Performance Catalysts
Abstract
Selective dissolution is a common corrosion process in dealloying in which an alloy is immersed in acid to remove the active element, leaving behind an inert constituent. We introduce this technique into the treatment of oxide catalysts. A three‐dimensionally ordered macroporous LaMnO 3 perovskite has been prepared and treated with diluted HNO 3 to selectively remove La cations, acquiring a novel γ‐MnO 2‐like material. LaMnO 3 is not a satisfactory catalyst on CO oxidation. Upon the removal of La cations, the obtained sample showed a significantly higher CO oxidation catalytic activity (T50=89 °C) than the initial precursor LaMnO 3 (T50=237 °C) and ordinary γ‐MnO 2 (T50=148 °C). A large surface area, a high degree of mesoporosity, excellent low‐temperature reducibility, and especially improved surface oxygen species are deduced to be responsible for CO oxidation at lower temperatures.
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Koh, S., & Strasser, P. (2007) · Journal of the American Chemical Society · doi:10.1021/ja0742784 · Cited by 783
Cited by
Oxygen Vacancy Promoted O2 Activation over Perovskite Oxide for Low-Temperature CO Oxidation
Yang, J., Hu, S., Fang, Y., Hoang, S., Li, L., Yang, W., Liang, Z., Wu, J., Hu, J., Xiao, W., et al. (2019) · ACS Catalysis · doi:10.1021/acscatal.9b02408 · Cited by 601
A facile method to promote LaMnO3 perovskite catalyst for combustion of methane
Ding, Y., Wang, S., Zhang, L., Chen, Z., Wang, M., & Wang, S. (2017) · Catalysis Communications · doi:10.1016/j.catcom.2017.04.022 · Cited by 83
Metadata
- Authors
- Si, W., Wang, Y., Peng, Y., & Li, J.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2015-05-12
- Volume
- 54
- Issue
- 27
- Pages
- 7954-7957
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2112860211
- Cited by
- 260
- References
- 1
- FWCI
- 6.53
- Type
- journal article
- Language
- en
- Open access
- closed
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- Si, W., Wang, Y., Peng, Y., & Li, J. (2015). Selective Dissolution of A‐Site Cations in ABO3 Perovskites: A New Path to High‐Performance Catalysts. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201502632
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